Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When Nitre touches any substance containing a Phlogiston, and actually
ignited, that is, actually on fire, it bursts out into a flame, burns,
and is decompounded with much noise.
In this deflagration the Acid is dissipated, and totally separated from
the Alkali, which now remains by itself.
Indeed the Acid, at least the greatest part of it, is by this means
quite destroyed. The Alkali which is left when Nitre is decompounded
by deflagration, is called in general _Fixed Nitre_, and, more
particularly, Nitre fixed by such and such a substance as was used
in the operation. But if Nitre be deflagrated with an inflammable
substance containing the vitriolic Acid, as sulphur, for instance,
the fixed Salt produced by the deflagration is not a pure Alkali, but
retains a good deal of the vitriolic Acid, and, by combining therewith,
hath now formed a neutral Salt.
Hitherto Chymists have been at a loss for the reason why Nitre flames,
and is decompounded in the manner above-mentioned, when it comes in
contact with a Phlogiston properly circumstanced. For my part, I
conjecture it to be for the same reason that vitriolated tartar is
also decompounded by the addition of a Phlogiston; _viz._ the Nitrous
Acid, having a greater affinity with the Phlogiston than with the
fixed Alkali, naturally quits the latter to join with the former, and
so produces a kind of sulphur, differing probably from the common
sulphur, formed by the vitriolic Acid, in that it is combustible to
such a degree, as to take fire and be consumed in the very moment of
its production; so that it is impossible to prevent its being thus
destroyed, and consequently impossible to save it. In support of this
opinion let it be considered, that the concurrence of the Phlogiston
is absolutely necessary to produce this deflagration, and that the
matter of pure fire is altogether incapable of effecting it: for though
Nitre be exposed to the most violent degree of fire, even that in the
focus of the most powerful burning-glass, it will not flame; nor will
that effect ever happen till the Nitre be brought into contact with a
Phlogiston properly so called, that is, the matter of fire existing
as a principle of some body; and it is moreover necessary that this
Phlogiston be actually on fire, and agitated with the igneous motion,
or else that the Nitre itself be red hot, and so penetrated with fire
as to kindle any inflammable matter that touches it.
This experiment, among others, helps to shew the distinction that ought
to be made between pure elementary fire, and fire become a principle of
bodies, to which we have given the name of Phlogiston.
Public-domain text, read in full here on John Shaqi.
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