Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Before we leave this subject, we shall observe, that Nitre deflagrates
only with such substances as contain the Phlogiston in its simplest and
purest form; such as charcoal, sulphur, and the metalline substances;
and that, though it will not deflagrate without the addition of some
combustible matter, it is nevertheless the only known body that will
burn, and make other combustibles burn with it, in close vessels,
without the admission of fresh air.
The Nitrous Acid hath not so great an affinity with earths and Alkalis
as the vitriolic Acid hath with the same substances; whence it follows
that the vitriolic Acid decomposes all neutral salts arising from
a combination of the Nitrous Acid with an earth or an Alkali. The
vitriolic Acids expells the Nitrous Acid, unites with the substance
which served it for a basis, and therewith forms a neutral salt, which
is an Alum, a Selenites, or a vitriolated Tartar, according to the
nature of that basis.
The Nitrous Acid, when thus separated from its basis by the vitriolic
Acid, is named _Spirit of Nitre_, or _Aqua Fortis_. If it be
dephlegmated, or contain but little superfluous water, it exhales in
reddish vapours; these vapours, being condensed and collected, form
a liquor of a brownish yellow, that incessantly emits vapours of the
same colour, and of a pungent disagreeable smell. These characters have
procured it the names of _Smoaking Spirit of Nitre_, and _Yellow Aqua
Fortis_. This property in the Nitrous Acid, of exhaling in vapours,
shews it to be less fixed than the vitriolic Acid; for the latter,
though ever so thoroughly dephlegmated, never yields any vapours, nor
has it any smell.
SECTION III.
_Of the_ ACID OF SEA-SALT.
The Acid of Sea-salt is so called because it is in fact obtained from
such Sea-salt as is used in our kitchens. It is not certainly known
in what this Acid differs from the vitriolic and the nitrous, with
regard to its constituent parts. Several of the ablest Chymists, such
as Becher and Stahl, are of opinion that the Marine Acid is no other
than the Universal Acid united to a particular principle which they
call a Mercurial Earth. Concerning this earth we shall have occasion
to say more, when we come to treat of metallic substances: but in the
mean time it must be owned, that the truth of this opinion is so far
from being proved by a sufficient number of experiments, that the
very existence of such a mercurial earth is not yet well established;
and therefore, that we may not exceed the bounds of our knowledge,
we shall content ourselves with delivering here the properties which
characterize the Acid in question, and by which it is distinguished
from the two others considered above.
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