Elements of the Theory and Practice of Chymistry, 5th ed. — John Shaqi
Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
When it is combined with absorbent earths, such as lime and chalk,
it forms a neutral salt that does not crystallize, and, when dried,
attracts the moisture of the air. If the absorbent earth be not fully
saturated with the Marine Acid, the salt thereby formed has the
properties of a fixed Alkali: and this is what made us say, when we
were on the subject of those salts, that they might be imitated by
combining an earth with an Acid. The Marine Acid, like the rest, hath
not so great an affinity with earths as with fixed Alkalis.
When it is combined with the latter, it forms a neutral salt which
shoots into cubical crystals. This salt is inclined to grow moist in
the air, and is consequently one of those which water dissolves in
equal quantities, at least as to sense, whether it be boiling hot or
quite cold.
The affinity of this Acid with Alkalis and absorbent Earths is not
so great as that of the vitriolic and nitrous Acids with the same
substances: whence it follows, that, when combined therewith, it may be
separated from them by either of those Acids.
The Acid of Sea-salt, thus disengaged from the substance which served
it for a basis, is called _Spirit of Salt_. When it contains but little
phlegm it is of a lemon colour, and continually emits many white, very
dense, and very elastic vapours; on which account it is named the
_Smoaking Spirit of Salt_. Its smell is not disagreeable, nor much
unlike that of saffron; but extremely quick and suffocating when it
smokes.
The Acid of Sea-salt, like the other two, seems to have a greater
affinity with the Phlogiston, than with fixed Alkalis. We are led
to this opinion by a very curious operation, which gives ground to
think that Sea-salt may be decomposed by the proper application of a
substance containing the Phlogiston.
From the Marine Acid combined with a Phlogiston results a kind
of Sulphur, differing from the common sort in many respects; but
particularly in this property, that it takes fire of itself upon
being exposed to the open air. This combination is called _English
Phosphorus_, _Phosphorus of Urine_, because it is generally prepared
from urine; or, only _Phosphorus_.
This combination of the Marine Acid with a Phlogiston is not easily
effected; because it requires a difficult operation in appropriated
vessels. For these reasons it does not always succeed; and Phosphorus
is so scarce and dear, that hitherto Chymists have not been able to
make on it the experiments necessary to discover all its properties. If
Phosphorus be suffered to burn away in the air, a small quantity of an
acid liquor may be obtained from it, which seems to be spirit of salt,
but either altered, or combined with some adventitious matter; for it
has several properties that are not to be found in the pure Marine
Acid; such as, leaving a fixed fusible substance behind it when exposed
to a strong fire, and being easily combined with the Phlogiston so as
to reproduce a Phosphorus.
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