Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Regulus of Antimony mixed with nitre, and projected into a red-hot
crucible, sets the nitre in a flame, and makes it detonate. As it
produces this effect by means of its phlogiston, it must needs at
the same time be calcined, and lose its metallic properties, which
accordingly happens, and when the nitre is in a triple proportion to
the Regulus, the latter is so perfectly calcined as to leave only a
white powder, which is fused with great difficulty, and then turns to a
faintly coloured glass, not very different from common glass, and which
is not reducible to a Regulus by the addition of inflammable matter;
at least it yields but a very small quantity thereof. If less nitre be
used, the calx is not so white; the glass it produces is more like a
metalline glass, and is more easily reduced. The calx of the Regulus
thus prepared by nitre is called, on account of the medicinal virtue
ascribed to it, _Diaphoretic Antimony_, or _Diaphoretic Mineral_.
Nitre always becomes an alkali by deflagration, and in the present
case retains part of the calx, which it even renders soluble in water.
This calx may be separated from the alkali, if an acid be employed to
precipitate it; and then it is called _Materia Perlata_. This pearly
matter is a calx of Antimony, so completely deprived of its phlogiston
as to be altogether incapable of reduction to a Regulus.
Regulus of Antimony readily joins and unites with sulphur, forming
therewith a compound which has a very faint metallic splendour.
This compound appears like a mass of long needles adhering together
laterally; and under this form it is usually found in the ore, or at
least when only separated by fusion from the stones and earthy matters
with which the ore is mixed. It is called _Crude Antimony_.
Antimony flows with a moderate heat, and becomes even more fluid than
other metallic substances. The action of fire dissipates or consumes
the sulphur it contains, and its phlogiston also, so as to convert it
into a calx and a glass, as it does the Regulus.
_Aqua regis_, which we observed to be the proper solvent of the
Regulus, being poured on Antimony, attacks and dissolves the reguline
part, but touches not the sulphur; in consequence whereof it decomposes
the Antimony, and separates its sulphur from its Regulus.
There are several other ways of effecting this decomposition, and
obtaining the reguline part of Antimony by itself: they consist either
in destroying the sulphureous part of the Antimony by combustion, or in
melting the Antimony with some substance which has a greater affinity
than its reguline part with sulphur. Most metals are very fit for this
latter purpose: for though the Regulus has a considerable affinity with
sulphur, yet all the metals, except Gold and Mercury, have a greater.
If therefore Iron, Copper, Lead, Silver, or Tin, be melted with
Antimony, the metal employed will unite with the sulphur, and separate
it from the Regulus.
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