Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
It must be observed, that, as these metals have some affinity with the
Regulus of Antimony, the Regulus will be joined in the operation by
some of the metal employed as a _Precipitant_, (so those substances
are called which serve as the means of separating two bodies from each
other); and therefore the Regulus procured in this manner will not be
absolutely pure: on this account care is taken to distinguish each by
adding the name of the metal employed in its precipitation; and thence
come these titles, _Martial Regulus of Antimony_, or only _Martial
Regulus_, _Regulus Veneris_; and so of the rest.
Antimony is employed with advantage to separate Gold from all the
other metals with which it may be alloyed. It has been shewn, that all
the metals have a greater affinity than the reguline part of Antimony
with sulphur, Gold only excepted; which is incapable of contracting
any union therewith: and therefore, if a mass compounded of Gold and
several other metals be melted with Antimony, every thing in that
mass which is not Gold will unite with the sulphur of the Antimony.
This union occasions two separations, to wit, that of the sulphur
of the Antimony from its reguline part, and that of the Gold from
the metals with which it was adulterated; and from the whole two new
compounds arise; namely, a combination of the metals with the sulphur,
which being lightest rises to the surface in fusion; and a metalline
mass, formed of the Gold and the reguline part of the Antimony united
together, which being much the heaviest sinks to the bottom. There is
no difficulty in parting the Gold from the Regulus of Antimony with
which it is alloyed: for the metalline mass needs only be exposed to a
degree of fire capable of dissipating into vapours all the Semi-metal
it contains; which being very volatile, the operation is much easier,
and more expeditiously finished, than if the metals with which the Gold
was debased were to be vitrified on the cupel; without taking into the
account, that, if Silver were one of them, recourse must needs be had
to the process of quartation after that of the cupel.
If equal parts of nitre and Antimony be mixed together, and the mixture
exposed to the action of fire, a violent detonation ensues; the nitre
deflagrating consumes the sulphur of the Antimony, and even a part of
its phlogiston. After the detonation there remains a greyish matter
which contains fixed nitre, vitriolated tartar, and the reguline part
of the Antimony in some measure deprived of its phlogiston, and half
vitrified by the action of the fire, which is considerably increased by
the deflagration. This matter is called _Liver of Antimony_.
If, instead of equal parts of nitre and Antimony, two parts of the
former be used to one of the latter, then the reguline part loses much
more of its phlogiston, and remains in the form of a yellowish powder.
Public-domain text, read in full here on John Shaqi.
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