Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
The saline character of Arsenic appears, first, from its being soluble
in water; secondly, from its corrosive quality, which makes it one
of the most violent poisons: a quality from which the other metallic
substances are free, when they are not combined with some saline
matter. Regulus of Antimony must however be excepted. But then the
best Chymists agree that this semi-metal is either nearly of the same
nature with Arsenic, or contains a portion thereof in its composition:
besides, its noxious qualities never discover themselves so plainly
as when it is combined with some acid. Lastly, Arsenic acts just like
the vitriolic acid upon nitre; that is, it decompounds that neutral
salt, by expelling its acid from its alkaline basis, of which it takes
possession, and therewith forms a new saline compound.
This combination is a species of salt that is perfectly neutral. When
the operation is performed in a close vessel, the salt shoots into
crystals in the form of right-angled quadrangular prisms, terminated at
each extremity by pyramids that are also quadrangular and right angled;
some of which however, instead of ending in a point, are obtuse as if
truncated. The consequence is different when the operation is performed
in an open vessel; for then nothing is obtained but an alkaline salt
impregnated with Arsenic, which cannot be crystallized.
The cause of this different effect is, that, when the Arsenic is once
engaged in the alkaline basis of the nitre, it can never be separated
from it by the utmost force of fire, so long as it is kept in a close
vessel; whereas, if you expose it to the fire without that precaution,
it readily separates from it. This property of arsenic was never before
observed by any Chymist, and therefore this our new species of Neutral
arsenical salt was absolutely unknown till lately.
This new salt possesses many singular properties, the chief of which
are these. First, it cannot be decompounded by the intervention of
any acid, even the strongest acid of vitriol; and this, joined to its
property of expelling the nitrous acid from its basis, shews that it
has a very great affinity with fixed alkalis.
Secondly, this very salt, on which pure acids have no effect, is
decompounded with the greatest ease by acids united with metallic
substances. The reason of this phenomenon is curious, and furnishes us
with an instance of what we advanced concerning double affinities.
If to a resolution of any metallic substance whatever, made by any acid
whatever, (except that of Mercury by the marine acid, and that of Gold
by _aqua regis_), a certain quantity of our New Salt dissolved in water
be added, the metallic substance is instantaneously separated from the
acid in which it was dissolved, and falls to the bottom of the liquor.
Public-domain text, read in full here on John Shaqi.
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