Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
All metallic precipitates obtained in this manner are found to be a
combination of the metal with Arsenic; whence it necessarily follows
that the new Neutral Salt is by this means decompounded, its arsenical
part uniting with the metallic substance, and its alkaline basis with
the acid in which that substance was dissolved.
The affinities of these several bodies must be considered as operating
on this occasion in the following manner: The acids which tend to
decompound the Neutral Salt of Arsenic, by virtue of their affinity
with its alkaline basis, are not able to accomplish it, because this
affinity is powerfully counteracted by that which the Arsenic has with
the same alkaline basis, and which is equal or even superior to theirs.
But if these acids happen to be united with a substance which naturally
has a very great affinity with the arsenical part of the Neutral Salt,
then, the two parts of which this Salt consists being drawn different
ways by two several affinities tending to separate them from each
other, the Salt will undergo a decomposition, which could not have been
effected without the help of this second affinity. Now, as metallic
substances have a great affinity with Arsenic, it is not surprising
that the Neutral Salt of Arsenic, which cannot be decompounded by a
pure acid, should nevertheless yield to an acid combined with a metal.
The decomposition of this Salt, therefore, and the precipitation which
of course it produces in metallic solutions, are brought about by the
means of a double affinity; namely, that of the acid with the alkaline
basis of the Neutral Salt, and that of the metal with the arsenical
part of that salt.
Arsenic has not the same effect on sea-salt as on nitre, and cannot
expel its acid: a very singular phenomenon, for which it is hard to
assign a reason; for the nitrous acid is known to have a greater
affinity than the marine acid with alkalis, and even with the basis of
sea-salt itself.
Yet Arsenic may be combined with the basis of sea-salt, and a Neutral
Salt thereby obtained, like that which results from the decomposition
of nitre by Arsenic: but for that purpose a quadrangular nitre must be
first prepared, and Arsenic applied thereto as to common nitre.
The Salt produced by uniting Arsenic with the basis of sea-salt very
much resembles the Neutral Salt of Arsenic above treated of as well in
the figure of its crystals as in its several properties.
Arsenic presents another singular phenomenon, both with the alkali of
nitre and with that of sea-salt; which is, that if it be combined with
these salts in a fluid state, it forms with them a saline compound,
quite different from the Neutral Salts of Arsenic which result from the
decomposition of nitrous salts.
Public-domain text, read in full here on John Shaqi.
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