Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
This saline compound, which I call _Liver of Arsenic_, takes up a
much greater quantity of Arsenic than is necessary for the perfect
saturation of the alkali. It has the appearance of a glue, which
is so much the thicker the more Arsenic it contains. Its smell is
disagreeable; it attracts the moisture of the air, and does not
crystallize; it is easily decompounded by any acid whatever, which
precipitates the Arsenic and unites with the alkali. Lastly, the
effects it produces on metallic solutions are different from those of
our neutral arsenical salts. But the bounds which I have set myself
in this treatise will not allow me to be more particular. Such as
have the curiosity to inquire further into the subject may consult my
Dissertations on Arsenic, published among the Memoirs of the Academy of
Sciences.
Arsenic is easily reduced to a Regulus. It need only be mixed with any
matter containing the phlogiston, and by the help of a moderate heat a
true Regulus will sublime. This Regulus, as was said, is very volatile,
and calcines with the greatest ease; which is the reason why it cannot
be obtained but in small quantities, and also why, in order to obtain
masses of it, some have thought of adding thereto some metal with which
it has a great affinity, such as Copper or Iron; because, by joining
with the metal, it is partly fixed and restrained from flying off. But
it is plain the Regulus obtained by this means is not pure, as it must
partake considerably of the metal employed.
Arsenic readily unites with sulphur, and rises with it in a yellow
compound, called _Orpiment_.
Sulphur cannot be separated from Arsenic but by the intervention of two
bodies only; to wit, a fixed alkali and Mercury.
The property which Mercury possesses of separating sulphur from Arsenic
is founded on this, that these two metallic substances are incapable
of contracting any union; whereas, though most of the other metals and
semi-metals have a greater affinity with sulphur than Mercury hath, as
was shewn in treating of the decomposition of Cinabar, nevertheless
they are all unable to decompound Orpiment; because some of them have
as great an affinity with Arsenic as with sulphur; others have no
affinity with either; and lastly, sulphur hath as great an affinity
with Arsenic as with any of them.
It must be observed that, if fixed alkalis be employed to purify
Arsenic in this manner, no more must be used than is necessary to
absorb the sulphur or the phlogiston, of which also it is their nature
to deprive Arsenic; for otherwise, as it has been shewn that Arsenic
readily unites with alkalis, they would absorb a considerable quantity
thereof.
CHAP. X.
_Of_ OIL _in general_.
Oil is an unctuous body, which burns and consumes with flame and smoke,
and is not soluble in water. It consists of the phlogiston united with
water by means of an acid. There is, moreover, in its composition a
certain proportion of earth, more or less, according to each several
sort of Oil.
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