Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Such bitumens or resins, as spirit of wine will not touch, are
dissolved in oils by means of fire, and then form another kind of
Varnish, which water does not hurt. These Varnishes are usually
coloured, and require much longer time to dry than the Spirit
Varnishes: they are called _Oil Varnishes_.
Spirit of wine hath a much greater affinity with water than with oily
matters: and therefore if a solution of any oil or resin in spirit of
wine be mixed with water, the liquor immediately grows turbid, and
acquires a whitish milky colour, owing entirely to the oily parts being
separated from the spirituous menstruum by the accession of water, and
too finely divided to appear in their natural form. But if the liquor
stand some time quiet, several of these particles unite together, and
gradually acquire a bulk sufficient to render them very perceptible to
the eye.
Acids have an affinity with spirit of wine, and may be combined with
it. By this union they lose most of their acidity, and on that account
are said to be _Dulcified_. But as these combinations of acids,
especially of the vitriolic acid, with spirit of wine furnish some new
productions of very singular properties, and as an examination thereof
may throw much light on the nature of ardent spirits, it will not be
amiss to take notice of them in this place, and consider each of them
particularly.
One part of highly concentrated oil of vitriol being mixed with four
parts of well dephlegmated spirit of wine, there arises immediately a
considerable ebullition and effervescence, attended with great heat,
and abundance of vapours, which smell pleasantly, but are hurtful to
the lungs. At the same time is heard a hissing like that produced by
a piece of red-hot iron plunged into water. Indeed it is proper to
mix the liquors very gradually; for otherwise the vessels in which the
operation is performed will be in great danger of breaking.
If the two liquors thus mixed be distilled with a very gentle heat,
there rises first a spirit of wine of a most penetrating and grateful
odour: when about half thereof is come over, what follows has a quicker
and more sulphureous smell, and is also more loaded with phlegm. When
the liquor begins to boil a little, there comes off a phlegm which
smells very strong of sulphur, and grows gradually more acid. On this
phlegm floats a small quantity of a very light and very limpid oil. In
the still there remains a thick blackish substance, somewhat like a
resin or bitumen. From this substance may be separated a good deal of a
vitriolic but sulphureous acid. When that is extracted, there remains
a black mass like a charred coal, which being put into a crucible, and
exposed to a violent heat, leaves a small portion of earth, very fixed,
and even vitrifiable.
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