Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
By rectifying the ardent spirit, which came over in distilling the
above-mentioned mixture, a very singular liquor is obtained, which
differs essentially both from oils and from ardent spirits, though
in certain respects it resembles them both. This liquor is known in
Chymistry by the name of _Æther_, and its chief properties are as
follow.
Æther is lighter, more volatile, and more inflammable, than the most
highly rectified spirit of wine. It quickly flies off when exposed
to the air, and suddenly catches fire when any flame approaches it.
It burns like spirit of wine without the least smoke, and consumes
entirely without leaving the smallest appearance of a coal or of ashes.
It dissolves oils and oily matters with great ease and rapidity. These
properties it has in common with an ardent spirit. But it resembles
an oil in that it is not miscible with water; and this makes it
essentially different from spirit of wine, the nature of which is to be
miscible with all aqueous liquors.
Another very singular property of Æther is its great affinity with
gold, exceeding even that of _aqua regis_. It does not indeed dissolve
gold when in a mass, and in its metalline form; but if a small quantity
of Æther be added to a solution of gold in _aqua regis_, and the whole
shaken together, the gold separates from the _aqua regis_, joins the
Æther, and remains dissolved therein.
The reason of all the phenomena above-mentioned, resulting from the
mixture of spirit of wine with oil of vitriol, is founded on the great
affinity between this acid and water. For if the vitriolic acid be
weak, and as it were over-dosed with watery parts, neither oil nor
Æther can be obtained by means thereof: but when highly concentrated,
it attracts the aqueous parts very powerfully; and therefore, being
mixed with spirit of wine, lays hold of most of the water contained
in it, and even robs it of some portion of that which is essential to
its nature, and necessary to constitute it spirit of wine: whence it
comes to pass, that a certain quantity of the oily particles in its
composition being separated from the watery particles, and so brought
nearer to each other, they unite and assume their natural form; and
thus the oil that swims at top of the sulphureous phlegm is produced.
The vitriolic acid moreover thickens and even burns some of this oil;
and hence comes the bituminous residuum left at the bottom of the
still, which looks like the result of a vitriolic acid combined with
common oil. Lastly, the vitriolic acid becomes sulphureous, as it
always doth when united with oily matters, and also very aqueous, on
account of the quantity of phlegm which it attracts from the spirit of
wine.
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