Elements of the Theory and Practice of Chymistry, 5th ed.Macquer, Pierre Joseph
History
Elements of the Theory and Practice of Chymistry, 5th ed.
Macquer, Pierre Joseph
Chemistry -- Early works to 1800
Æther may be considered as a spirit of wine exceedingly dephlegmated,
even to such a degree that its nature is thereby changed; so that the
few aqueous particles left in it are not sufficient to dissolve the
oily particles and keep them asunder; which therefore being now much
nearer to one another than in common spirit of wine, the liquor hath
lost its property of being miscible with water.
Spirit of nitre well dephlegmated, and combined with spirit of wine,
presents likewise some very singular appearances.
First, in the very instant of its mixture with spirit of wine, it
produces a greater and more violent effervescence than the vitriolic
acid occasions.
Secondly, this mixture, without the help of distillation, and only by
stopping the bottle in which the liquors are contained, affords a sort
of Æther, produced probably by the vapours which ascend from, and swim
at top of the mixture. This is a very singular liquor. Dr. Navier was
the first that took notice of it, and gave a description thereof, which
may be seen in the Memoirs of the Academy of Sciences.
Thirdly, some authors pretend that, by distilling the mixture under
consideration, an oil is obtained greatly resembling that which, as we
observed above, rises from spirit of wine combined with the vitriolic
acid: others again deny this. For my part, I believe the thing depends
on the different concentration of the spirit of nitre, as well as on
the quality of the spirit of wine, which is sometimes more sometimes
less oily.
Fourthly, the two liquors we are speaking of, being intimately mixed by
distillation, form a liquor slightly acid, used in medicine, and known
by the name of _Sweet_ or _Dulcified Spirit of Nitre_: a very proper
name, seeing the nitrous acid, by uniting with the spirit of wine,
actually loses almost all its acidity and corrosive quality.
Fifthly and lastly, when the distillation is finished, there remains in
the bottom of the vessel a thick blackish substance, nearly resembling
that which is found after distilling oil of vitriol and spirit of wine.
Spirit of salt hath likewise been combined with spirit of wine; but it
does not unite therewith so easily or so intimately as the two acids
above-mentioned. To mix them thoroughly, the spirit of salt must be
highly concentrated, and smoking, and moreover the assistance of the
still must be called in. Some authors pretend that from this mixture
also a small quantity of oil may be obtained; which probably happens
when the liquors have the qualities above-specified. The marine acid
likewise, by uniting with spirit of wine, loses most of its acidity; on
which account it is in like manner called _Sweet_ or _Dulcified Spirit
of Salt_. A thick residuum is also found here after distillation.
CHAP. XIV.
_Of the_ ACETOUS FERMENTATION.
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