The quantity [alpha] is then called the temperature-coefficient, and
its reciprocal is the temperature at which the resistivity would
become zero. By an extension of this notion we can call the quantity
d[rho]/[rho]dt the temperature coefficient corresponding to any
temperature t at which the resistivity is [rho]. In all cases the
relation between the resistivity of a substance and the temperature is
best set out in the form of a curve called a temperature-resistance
curve. If a series of such curves are drawn for various pure metals,
temperature being taken as abscissa and resistance as ordinate, and if
the temperature range extends from the absolute zero of temperature
upwards, then it is found that these temperature-resistance lines are
curved lines having their convexity either upwards or downwards. In
other words, the second differential coefficient of resistance with
respect to temperature is either a positive or negative quantity. An
extensive series of observations concerning the form of the
resistivity curves for various pure metals over a range of temperature
extending from -200° C. to +200° C. was carried out in 1892 and 1893
by Fleming and Dewar (_Phil. Mag._ Oct. 1892 and Sept. 1893). The
resistance observations were taken with resistance coils constructed
with wires of various metals obtained in a state of great chemical
purity. The lengths and mean diameters of the wires were carefully
measured, and their resistance was then taken at certain known
temperatures obtained by immersing the coils in boiling aniline,
boiling water, melting ice, melting carbonic acid in ether, and
boiling liquid oxygen, the temperatures thus given being +184°.5 C.,
+100° C., 0° C., -78°.2 C. and -182°.5 C. The resistivities of the
various metals were then calculated and set out in terms of the
temperature. From these data a chart was prepared showing the
temperature-resistance curves of these metals throughout a range of
400 degrees. The exact form of these curves through the region of
temperature lying between -200° C. and -273° C. is not yet known. As
shown on the chart, the curves evidently do not converge to precisely
the same point. It is, however, much less probable that the resistance
of any metal should vanish at a temperature above the absolute zero
than at the absolute zero itself, and the precise path of these curves
at their lower ends cannot be delineated until means are found for
fixing independently the temperature of some regions in which the
resistance of metallic wires can be measured. Sir J. Dewar
subsequently showed that for certain pure metals it is clear that the
resistance would not vanish at the absolute zero but would be reduced
to a finite but small value (see "Electric Resistance Thermometry at
the Temperature of Boiling Hydrogen," _Proc. Roy. Soc._ 1904, 73, p.
244).
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