The resistivity curves of the magnetic metals are also remarkable for
the change of curvature they exhibit at the magnetic critical
temperature. Thus J. Hopkinson and D. K. Morris (_Phil. Mag._
September 1897, p. 213) observed the remarkable alteration that takes
place in the iron resistance temperature curve in the neighbourhood of
780° C. At that temperature the direction of the curvature of the
curve changes so that it becomes convex upwards instead of convex
downwards, and in addition the value of the temperature coefficient
undergoes a great reduction. The mean temperature coefficient of iron
in the neighbourhood of 0° C. is 0.0057; at 765° C. it rises to a
maximum value 0.0204; but at 1000° C. it falls again to a lower value,
0.00244. A similar rise to a maximum value and subsequent fall are
also noted in the case of the specific heat of iron. The changes in
the curvature of the resistivity curves are undoubtedly connected with
the molecular changes that occur in the magnetic metals at their
critical temperatures.
A fact of considerable interest in connexion with resistivity is the
influence exerted by a strong magnetic field in the case of some
metals, notably bismuth. It was discovered by A. Righi and confirmed
by S. A. Leduc (_Journ. de Phys._ 1886, 5, p. 116, and 1887, 6, p.
189) that if a pure bismuth wire is placed in a magnetic field
transversely to the direction of the magnetic field, its resistance is
considerably increased. This increase is greatly affected by the
temperature of the metal (Dewar and Fleming, _Proc. Roy. Soc._ 1897,
60, p. 427). The temperature coefficient of pure copper is an
important constant, and its value as determined by Messrs Clark, Forde
and Taylor in terms of Fahrenheit temperature is
[rho]t = [rho]32 {1 + 0.0023708(t - 32) + 0.0000034548(t - 32)²}.
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