_Direct Measurement of Ionic Velocities._--Sir Oliver Lodge was the
first to directly measure the velocity of an ion (_B.A. Report_, 1886,
p. 389). In a horizontal glass tube connecting two vessels filled with
dilute sulphuric acid he placed a solution of sodium chloride in solid
agar-agar jelly. This solid solution was made alkaline with a trace of
caustic soda in order to bring out the red colour of a little
phenol-phthalein added as indicator. An electric current was then passed
from one vessel to the other. The hydrogen ions from the anode vessel of
acid were thus carried along the tube, and, as they travelled,
decolourized the phenol-phthalein. By this method the velocity of the
hydrogen ion through a jelly solution under a known potential gradient
was observed to about 0.0026 cm. per sec, a number of the same order as
that required by Kohlrausch's theory. Direct determinations of the
velocities of a few other ions have been made by W. C. D. Whetham
(_Phil. Trans._ vol. 184, A, p. 337; vol. 186, A, p. 507; _Phil. Mag._,
October 1894). Two solutions having one ion in common, of equivalent
concentrations, different densities, different colours, and nearly equal
specific resistances, were placed one over the other in a vertical glass
tube. In one case, for example, decinormal solutions of potassium
carbonate and potassium bichromate were used. The colour of the latter
is due to the presence of the bichromate group, Cr2O7. When a current
was passed across the junction, the anions CO3 and Cr2O7 travelled in
the direction opposite to that of the current, and their velocity could
be determined by measuring the rate at which the colour boundary moved.
Similar experiments were made with alcoholic solutions of cobalt salts,
in which the velocities of the ions were found to be much less than in
water. The behaviour of agar jelly was then investigated, and the
velocity of an ion through a solid jelly was shown to be very little
less than in an ordinary liquid solution. The velocities could therefore
be measured by tracing the change in colour of an indicator or the
formation of a precipitate. Thus decinormal jelly solutions of barium
chloride and sodium chloride, the latter containing a trace of sodium
sulphate, were placed in contact. Under the influence of an
electromotive force the barium ions moved up the tube, disclosing their
presence by the trace of insoluble barium sulphate formed. Again, a
measurement of the velocity of the hydrogen ion, when travelling through
the solution of an acetate, showed that its velocity was then only about
the one-fortieth part of that found during its passage through
chlorides. From this, as from the measurements on alcohol solutions, it
is clear that where the equivalent conductivities are very low the
effective velocities of the ions are reduced in the same proportion.
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