Another series of direct measurements has been made by Orme Masson
(_Phil. Trans._ vol. 192, A, p. 331). He placed the gelatine solution of
a salt, potassium chloride, for example, in a horizontal glass tube, and
found the rate of migration of the potassium and chlorine ions by
observing the speed at which they were replaced when a coloured anion,
say, the Cr2O7 from a solution of potassium bichromate, entered the tube
at one end, and a coloured cation, say, the Cu from copper sulphate, at
the other. The coloured ions are specifically slower than the colourless
ions which they follow, and in this case it follows that the coloured
solution has a higher resistance than the colourless. For the same
current, therefore, the potential gradient is higher in the coloured
solution and lower in the colourless one. Thus a coloured ion which gets
in front of the advancing boundary finds itself acted on by a smaller
force and falls back into line, while a straggling colourless ion is
pushed forward again. Hence a sharp boundary is preserved. B. D. Steele
has shown that with these sharp boundaries the use of coloured ions is
unnecessary, the junction line being visible owing to the difference in
the optical refractive indices of two colourless solutions. Once the
boundary is formed, too, no gelatine is necessary, and the motion can be
watched through liquid aqueous solutions (see R. B. Denison and B. D.
Steele, _Phil. Trans._, 1906).
All the direct measurements which have been made on simple binary
electrolytes agree with Kohlrausch's results within the limits of
experimental error. His theory, therefore, probably holds good in such
cases, whatever be the solvent, if the proper values are given to the
ionic velocities, i.e. the values expressing the velocities with which
the ions actually move in the solution of the strength taken, and under
the conditions of the experiment. If we know the specific velocity of
any one ion, we can deduce, from the conductivity of very dilute
solutions, the velocity of any other ion with which it may be
associated, a proceeding which does not involve the difficult task of
determining the migration constant of the compound. Thus, taking the
specific ionic velocity of hydrogen as 0.00032 cm. per second, we can
find, by determining the conductivity of dilute solutions of any acid,
the specific velocity of the acid radicle involved. Or again, since we
know the specific velocity of silver, we can find the velocities of a
series of acid radicles at great dilution by measuring the conductivity
of their silver salts.
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