During this work the question arose naturally: How far does the
_exactness_ of the law extend? It is well known that most natural laws
are only approximations, owing to disturbing causes. Are there
disturbing causes also with atomic weights? The answer is that as far as
we know there are none. The law is still an exact one. But we must keep
in mind that an absolute answer is never possible. Our exactness is in
every case limited, and as long as the possible variations lie behind
this limit, we cannot tell anything about them. In recent times H.
Landolt has doubted and experimentally investigated the law of the
conservation of weight.
Landolt's experiments were carried out in vessels of the shape of an
inverted U, each branch holding one of the substances to react one on
the other. Two vessels were prepared as equal as possible and hung on
both sides of a most sensitive balance. Then the difference of weight
was determined in the usual way by exchanging both the vessels on the
balance. After this set of weighings one of the vessels was inverted and
the chemical reaction between the contained substances was performed;
then the double weighing was repeated. Finally also the second vessel
was inverted and a third set of weighings taken. From blank experiments
where the vessels were filled with substances which did not react one on
the other, the maximum error was determined to 0.03 milligramme. The
reactions experimented with were: silver salts with ferrous sulphate;
iron on copper sulphate; gold chloride and ferrous chloride; iodic acid
and hydriodic acid; iodine and sodium sulphite; uranyl nitrate and
potassium hydrate; chloral hydrate and potassium hydrate; electrolysis
of cadmium iodide by an alternating current; solution of ammonium
chloride, potassium bromide and uranyl nitrate in water, and
precipitation of an aqueous solution of copper sulphate by alcohol. In
most of these experiments a slight diminution of weight was observed
which exceeded the limit of error distinctly in two cases, viz. silver
nitrate with ferrous sulphate and iodic acid with hydriodic acid, the
loss of weight amounting from 0.068 to 0.199 mg. with the first and
0.047 to 0.177 mg. with the second reaction on about 50 g. of substance.
As each of these reactions had been tried in nine independent
experiments, Landolt felt certain that there was no error of observation
involved. But when the vessels were covered inside with paraffin wax, no
appreciable diminution of weight was observed.
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