The change of temperature due to the Thomson-Joule effect varies in
amount with different gases, or rather with the temperature at which the
operation is conducted. At ordinary temperatures oxygen and carbonic
acid are cooled, while hydrogen is slightly heated. But hydrogen also is
cooled if before being passed through the nozzle or plug it is brought
into a thermal condition comparable to that of other gases at ordinary
temperatures--that is to say, when it is initially cooled to a
temperature having the same ratio to its critical point as their
temperatures have to their critical points--and similarly the more
condensible gases would be heated, and not cooled, by passing through a
nozzle or plug if they were employed at a temperature sufficiently above
their critical points. Each gas has therefore a point of inversion of
the Thomson-Joule effect, and this temperature is, according to the
theory of van der Waals, about 6.75 times the critical temperature of
the body. Olszewski has determined the inversion-point in the case of
hydrogen, and finds it to be 192.5° absolute, the theoretical critical
point being thus about 28.5° absolute. The cooling effect obtained is
small, being for air about ¼° C. per atmosphere difference of pressure
at ordinary temperatures. But the decrement of temperature is
proportional to the difference of pressure and inversely as the absolute
temperature, so that the Thomson-Joule effect increases rapidly by the
combined use of a lower temperature and greater difference of gas
pressure. By means of the "regenerative" method of working, which was
described by C. W. Siemens in 1857, developed and extended by Ernest
Solvay in 1885, and subsequently utilized by numerous experimenters in
the construction of low temperature apparatus, a practicable liquid air
plant was constructed by Linde. The gas which has passed the orifice and
is therefore cooled is made to flow backwards round the tube that leads
to the nozzle; hence that portion of the gas that is just about to pass
through the nozzle has some of its heat abstracted, and in consequence
on expansion is cooled to a lower temperature than the first portion. In
its turn it cools a third portion in the same way, and so the reduction
of temperature goes on progressively until ultimately a portion of the
gas is liquefied. Apparatus based on this principle has been employed
not only by Linde in Germany, but also by Tripler in America and by
Hampson and Dewar in England. The last-named experimenter exhibited in
December 1895 a laboratory machine of this kind (fig. 2), which when
supplied with oxygen initially cooled to -79° C., and at a pressure of
100-150 atmospheres, began to yield liquid in about a quarter of an hour
after starting. The initial cooling is not necessary, but it has the
advantage of reducing the time required for the operation. The
efficiency of the Linde process is small, but it is easily conducted and
only requires plenty of cheap power.
Public-domain text, read in full here on John Shaqi.
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