When we can work turbines or other
engines at low temperatures, so as to effect cooling through the
performance of external work, then the economy in the production of
liquid air and hydrogen will be greatly increased.
[Illustration: FIG. 3.--Hydrogen Jet Apparatus. A, Cylinder containing
compressed hydrogen. B and C, Vacuum vessels containing carbonic acid
under exhaustion and liquid air respectively. D, Regenerating coil in
vacuum vessel. F, Valve. G, Pin-hole nozzle.]
This treatment was next extended to hydrogen. For the reason already
explained, it would have been futile to experiment with this substance
at ordinary temperatures, and therefore as a preliminary it was cooled
to the temperature of boiling liquid air, about -190° C. At this
temperature it is still 2½ times above its critical temperature, and
therefore its liquefaction in these circumstances would be comparable to
that of air, taken at +60° C., in an apparatus like that just described.
Dewar showed in 1896 that hydrogen cooled in this way and expanded in a
regenerative coil from a pressure of 200 atmospheres was rapidly reduced
in temperature to such an extent that after the apparatus had been
working a few minutes the issuing jet was seen to contain liquid, which
was sufficiently proved to be liquid hydrogen by the fact that it was so
cold as to freeze liquid air and oxygen into hard white solids. Though
with this apparatus, a diagrammatic representation of which is shown in
fig. 3, it was now found possible at the time to collect the liquid in
an open vessel, owing to its low specific gravity and the rapidity of
the gas-current, still the general type of the arrangement seemed so
promising that in the next two years there was laid down in the
laboratories of the Royal Institution a large plant--it weighs 2 tons
and contains 3000 ft. of pipe--which is designed on precisely the same
principles, although its construction is far more elaborate. The one
important novelty, without which it is practically impossible to
succeed, is the provision of a device to surmount the difficulty of
withdrawing the liquefied hydrogen after it has been made. The
desideratum is really a means of forming an aperture in the bottom of a
vacuum vessel by which the contained liquid may be run out. For this
purpose the lower part of the vacuum vessel (D in fig. 3) containing the
jet is modified as shown in fig. 4; the inner vessel is prolonged in a
fine tube, coiled spirally, which passes through the outer wall of the
vacuum vessel, and thus sufficient elasticity is obtained to enable the
tube to withstand without fracture the great contraction consequent on
the extreme cold to which it is subjected. Such peculiarly shaped vacuum
vessels were made by Dewar's directions in Germany, and have
subsequently been supplied to and employed by other experimenters.
[Illustration: FIG. 4.--Bottom of Vacuum Vessel.]
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