_Air._--Seeing that the boiling-points of nitrogen and oxygen are
different, it might be expected that on the liquefaction of
atmospheric air the two elements would appear as two separate liquids.
Such, however, is not the case; they come down simultaneously as one
homogeneous liquid. Prepared on a large scale, liquid air may contain
as much as 50% of oxygen when collected in open vacuum-vessels, but
since nitrogen is the more volatile it boils off first, and as the
liquid gradually becomes richer in oxygen the temperature at which it
boils rises from about -192° C. to about -182° C. At the former
temperature it has a density of about 0.910. It is a non-conductor of
electricity. Properly protected from external heat, and subjected to
high exhaustion, liquid air becomes a stiff transparent jelly-like
mass, a magma of solid nitrogen containing liquid oxygen, which may
indeed be extracted from it by means of a magnet, or by rapid rotation
of the vacuum vessel in imitation of a centrifugal machine. The
temperature of this solid under a vacuum of about 14 mm. is -216°. At
the still lower temperatures attainable by the aid of liquid hydrogen
it becomes a white solid, having, like solid oxygen, a faint blue
tint. The refractive index of liquid air is 1.2068.
_Fluorine_, prepared in the free state by Moissan's method of
electrolysing a solution of potassium fluoride in anhydrous
hydrofluoric acid, was liquefied in the laboratories of the Royal
Institution, London, in 1897. Exposed to the temperature of
quietly-boiling liquid oxygen, the gas did not change its state,
though it lost much of its chemical activity, and ceased to attack
glass. But a very small vacuum formed over the oxygen was sufficient
to determine liquefaction, a result which was also obtained by cooling
the gas to the temperature of freshly-made liquid air boiling at
atmospheric pressure. Hence the boiling-point is fixed at about -187°
C. The liquid is of a clear yellow colour, possessing great mobility.
Its density is 1.14, and its capillarity rather less than that of
liquid oxygen. The liquid, when examined in a thickness of 1 cm., does
not show any absorption bands, and it is not attracted by a magnet.
Cooled in liquid hydrogen it is frozen to a white solid, melting at
about 40° abs.
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