_Hydrogen._--Liquid hydrogen is the lightest liquid known to the
chemist, having a density slightly less than 0.07 as compared with
water, and being six times lighter than liquid marsh-gas, which is
next in order of lightness. One litre weighs only 70 grammes, and 1
gramme occupies a volume of 14-15 cc. In spite of its extreme
lightness, however, it is easily seen, has a well-defined meniscus and
drops well. At its boiling-point the liquid is only 55 times denser
than the vapour it is giving off, whereas liquid oxygen in similar
condition is 258 times denser than its vapour, and nitrogen 177 times.
Its atomic volume is about 14.3, that of liquid oxygen being 13.7,
and that of liquid nitrogen 16.6, at their respective boiling-points.
Its latent heat of vaporization about the boiling-point is about 121
gramme-calories, and the latent heat of fluidity cannot exceed 16
units, but may be less. Hydrogen appears to have the same specific
heat in the liquid as in the gaseous state, about 3.4. Its surface
tension is exceedingly low, about one-fifth that of liquid air at its
boiling-point, or one-thirty-fifth that of water at ordinary
temperatures, and this is the reason that bubbles formed in the liquid
are so small as to give it an opalescent appearance during ebullition.
The liquid is without colour, and gives no absorption spectrum.
Electric sparks taken in the liquid between platinum poles give a
spectrum showing the hydrogen lines C and F bright on a background of
continuous spectrum. Its refractive index at the boiling-point has
theoretically the value 1.11. It was measured by determining the
relative difference of focus for a parallel beam of light sent through
a spherical vacuum vessel filled successively with water, liquid
oxygen and liquid hydrogen; the result obtained was 1.12. Liquid
hydrogen is a non-conductor of electricity. The precise determination
of its boiling-point is a matter of some difficulty. The first results
obtained from the use of a platinum resistance thermometer gave -238°
C., while a similar thermometer made with an alloy of rhodium-platinum
indicated a value 8 degrees lower. Later, a gold thermometer indicated
about -249° C., while with an iron one the result was only -210° C. It
was thus evident that electrical resistance thermometers are not to be
trusted at these low temperatures, since the laws correlating
resistance and temperature are not known for temperatures at and below
the boiling-point of hydrogen, though they are certainly not the same
as those which hold good higher up the thermometric scale. The same
remarks apply to the use of thermo-electric junctions at such
exceptional temperatures. Recourse was therefore had to a
constant-volume hydrogen thermometer, working under reduced pressure,
experiments having shown that such a thermometer, filled with either a
simple or a compound gas (e.g.
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