Dewar used pure metallic lead for the purpose of conveying definite
amounts of heat to liquid gas calorimeters of this kind, that metal
being selected on the ground of the small variation in its specific heat
at low temperatures. He was thus able to determine the latent heats of
evaporation of liquid oxygen, nitrogen and hydrogen directly at their
boiling points, and he also ascertained the specific heats of a large
number of inorganic and organic bodies, and of some gases in the solid
state, such as carbon dioxide, sulphurous acid and ammonia. Perhaps his
most interesting results were those which showed the variation in the
specific heats of diamond, graphite and ice as typical bodies (table
X.). With Professor Curie he used both the liquid oxygen and the liquid
hydrogen calorimeter for preliminary measurements of the rate at which
radium bromide gives out energy at low temperatures. The quantity of the
salt available was 0.42 gram, and the thermal evolutions were as
follows:--
Gas evolved Calories
per minute. per hour.
Liquid oxygen 5.5 cc. 22.8 \
Liquid hydrogen 51.0 " 31.6 > Crystals.
Melting ice .. 24.1 /
Liquid oxygen 2.0 " 8.3 After fusion.
Liquid oxygen 2.5 " 10.3 Emanation condensed.
The apparent increase of heat evolution at the temperature of liquid
hydrogen was probably due to the calorimeter being too small; hydrogen
spray was thus carried away with the gas, making the volume of gas too
great and inferentially also the heat evolved.
Liquid air and liquid hydrogen calorimeters open up an almost unlimited
field of research in the determination of specific heats and other
thermal constants, and are certain to become common laboratory
instruments for such purposes.
Public-domain text, read in full here on John Shaqi.
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