_Chemical Action._--By extreme cold chemical action is enormously
reduced, though it may not in all cases be entirely abolished even at
the lowest temperatures yet attained; one reason for this diminution of
activity may doubtless be sought in the fact that in such conditions
most substances are solid, that is, in the state least favourable to
chemical combination. Thus an electric pile of sodium and carbon ceases
to yield a current when immersed in liquid oxygen. Sulphur, iron and
other substances can be made to burn under the surface of liquid oxygen
if the combustion is properly established before the sample is immersed,
and the same is true of a fragment of diamond. Nitric oxide in the
gaseous condition combines instantly with free oxygen, producing the
highly-coloured gas, nitric peroxide, but in the solid condition it may
be placed in contact with liquid oxygen without showing any signs of
chemical action. If the combination of a portion of the mixture is
started by elevation of temperature, then detonation may take place
throughout the cooled mass. The stability of endothermic bodies like
nitric oxide and ozone at low temperatures requires further
investigation. The behaviour of fluorine, which may be regarded as the
most active of the elements, is instructive in this respect. As a gas,
cooled to -180° C. it loses the power of attacking glass; similarly
silicon, borax, carbon, sulphur and phosphorus at the same temperature
do not become incandescent in an atmosphere of the gas. Passed into
liquid oxygen, the gas dissolves and imparts a yellowish tint to the
liquid; if the oxygen has been exposed to the air for some hours, the
fluorine produces a white flocculent precipitate, which if separated by
filtering deflagrates with violence as the temperature rises. It appears
to be a hydrate of fluorine. As a liquid at -210° fluorine attacks
turpentine also cooled to that temperature with explosive force and the
evolution of light, while the direction of a jet of hydrogen upon its
surface is immediately followed by combination and a flash of flame.
Even when the point of a tube containing solid fluorine is broken off
under liquid hydrogen, a violent explosion ensues.
_Photographic Action._--The action of light on photographic plates,
though greatly diminished at -180°, is far from being in abeyance; an
Eastman film, for instance, remains fairly sensitive at -210°. At the
still lower temperature of liquid hydrogen the photographic activity is
reduced to about half what it is at that of liquid air; in other words,
about 10% of the original sensitivity remains. Experiments carried out
with an incandescent lamp, a Röntgen bulb and the ultra-violet spark
from magnesium and cadmium, to discover at what distances from the
source of light the plates must be placed in order to receive an equal
photographic impression, yielded the results shown in table XI.
TABLE XI.
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