pumps working in series. In this way he added six substances, usually
gaseous, to the list of those that could be obtained in the liquid
state, and reduced seven, including ammonia, nitrous oxide and
sulphuretted hydrogen, into the solid form, at the same time effecting a
number of valuable determinations of vapour tensions. But he failed to
condense oxygen, nitrogen and hydrogen, the original objects of his
pursuit, though he found reason to think that "further diminution of
temperature and improved apparatus for pressure may very well be
expected to give us these bodies in the liquid or solid state." His
surmise that increased pressure alone would not suffice to bring about
change of state in these gases was confirmed by subsequent
investigators, such as M. P. E. Berthelot, who in 1850 compressed oxygen
to 780 atmospheres (_Ann. chim. phys._, 1850, 30, p. 237), and Natterer,
who a few years later subjected the permanent gases to a pressure of
2790 atmospheres, without result; and in 1869 Thomas Andrews (_Phil.
Trans._, 11) by his researches on carbonic acid finally established the
conception of the "critical temperature" as that temperature, differing
for different bodies, above which no gas can be made to assume the
liquid state, no matter what pressure it be subjected to (see
CONDENSATION OF GASES).
About 1877 the problem of liquefying the permanent gases was taken up by
L. P. Cailletet and R. P. Pictet, working almost simultaneously though
independently. The former relied on the cold produced by the sudden
expansion of the gases at high compression. By means of a specially
designed pump he compressed about 100 cc. of oxygen in a narrow glass
tube to about 200 atmospheres, at the same time cooling it to about -29°
C., and on suddenly releasing the pressure he saw momentarily in the
interior of the tube a mist (_brouillard_), from which he inferred the
presence of a vapour very near its point of liquefaction. A few days
later he repeated the experiment with hydrogen, using a pressure of
nearly 300 atmospheres, and observed in his tube an exceedingly fine and
subtle fog which vanished almost instantaneously. At the time when these
experiments were carried out it was generally accepted that the mist or
fog consisted of minute drops of the liquefied gases. Even had this been
the case, the problem would not have been completely solved, for
Cailletet was unable to collect the drops in the form of a true stable
liquid, and at the best obtained a "dynamic" not a "static" liquid, the
gas being reduced to a form that bears the same relation to a true
liquid that the partially condensed steam issuing from the funnel of a
locomotive bears to water standing in a tumbler. But subsequent
knowledge showed that even this proximate liquefaction could not have
taken place, and that the fog could not have consisted of drops of
liquid hydrogen, because the cooling produced by the adiabatic expansion
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