would give a temperature of only 44° abs., which is certainly above the
critical temperature of hydrogen. Pictet again announced that on opening
the tap of a vessel containing hydrogen at a pressure of 650 atmospheres
and cooled by the cascade method (see CONDENSATION OF GASES) to -140°
C., he saw issuing from the orifice an opaque jet which he assumed to
consist of hydrogen in the liquid form or in the liquid and solid forms
mixed. But he was no more successful than Cailletet in collecting any of
the liquid, which--whatever else it may have been, whether ordinary air
or impurities associated with the hydrogen--cannot have been hydrogen
because the means he employed were insufficient to reduce the gas to
what has subsequently been ascertained to be its critical point, below
which of course liquefaction is impossible. It need scarcely be added
that if the liquefaction of hydrogen be rejected a fortiori Pictet's
claim to have effected its solidification falls to the ground.
After Cailletet and Pictet, the next important names in the history of
the liquefaction of gases are those of Z. F. Wroblewski and K. S.
Olszewski, who for some years worked together at Cracow. In April 1883
the former announced to the French Academy that he had obtained oxygen
in a completely liquid state and (a few days later) that nitrogen at a
temperature of -136° C., reduced suddenly from a pressure of 150
atmospheres to one of 50, had been seen as a liquid which showed a true
meniscus, but disappeared in a few seconds. But with hydrogen treated in
the same way he failed to obtain even the mist reported by Cailletet. At
the beginning of 1884 he performed a more satisfactory experiment.
Cooling hydrogen in a capillary glass tube to the temperature of liquid
oxygen, he expanded it quickly from 100 atmospheres to one, and
obtained the appearance of an instantaneous ebullition. Olszewski
confirmed this result by expanding from a pressure of 190 atmospheres
the gas cooled by liquid oxygen and nitrogen boiling under reduced
pressure, and even announced that he saw it running down the walls of
the tube as a colourless liquid.
Public-domain text, read in full here on John Shaqi.
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