_Vacuum Vessels._--The problem involved in the liquefaction of hydrogen
was in reality a double one. In the first place, the gas had to be
cooled to such a temperature that the change to the liquid state was
rendered possible. In the second, means had to be discovered for
protecting it, when so cooled, from the influx of external heat, and
since the rate at which heat is transferred from one body to another
increases very rapidly with the difference between their temperatures,
the question of efficient heat insulation became at once more difficult
and more urgent in proportion to the degree of cold attained. The second
part of the problem was in fact solved first. Of course packing with
non-conducting materials was an obvious expedient when it was not
necessary that the contents of the apparatus should be visible to the
eye, but in the numerous instances when this was not the case such
measures were out of the question. Attempts were made to secure the
desired end by surrounding the vessel that contained the cooled or
liquid gas with a succession of other vessels, through which was
conducted the vapour given off from the interior one. Such devices
involved awkward complications in the arrangement of the apparatus, and
besides were not as a rule very efficient, although some workers, e.g.
Dr Kamerlingh Onnes, of Leiden, reported some success with their use. In
1892 it occurred to Dewar that the principle of an arrangement he had
used nearly twenty years before for some calorimetric experiments on the
physical constants of hydrogenium, which was a natural deduction from
the work of Dulong and Petit on radiation, might be employed with
advantage as well to protect cold substances from heat as hot ones from
cold. He therefore tried the effect of surrounding his liquefied gas
with a highly exhausted space. The result was entirely successful.
Experiment showed that liquid air contained in a glass vessel with two
walls, the space between which was a high vacuum, evaporated at only one
fifth the rate it did when in an ordinary vessel surrounded with air at
atmospheric pressure, the convective transference of heat by means of
the gas particles being enormously reduced owing to the vacuum. But in
addition these vessels lent themselves to an arrangement by which
radiant heat could still further be cut off, since it was found that
when the inner wall was coated with a bright deposit of silver, the
influx of heat was diminished to one-sixth of the amount existing
without the metallic coating. The total effect, therefore, of the high
vacuum and silvering is to reduce the in-going heat to one-thirtieth
part. In making such vessels a mercurial vacuum has been found very
satisfactory. The vessel in which the vacuum is to be produced is
provided with a small subsidiary vessel joined by a narrow tube with the
main vessel, and connected with a powerful air-pump. A quantity of
mercury having been placed in it, it is heated in an oil- or air-bath to
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