about 200° C., so as to volatilize the mercury, the vapour of which is
removed by the pump. After the process has gone on for some time, the
pipe leading to the pump is sealed off, the vessel immediately removed
from the bath, and the small subsidiary part immersed in some cooling
agent such as solid carbonic acid or liquid air, whereby the mercury
vapour is condensed in the small vessel and a vacuum of enormous tenuity
left in the large one. The final step is to seal off the tube connecting
the two. In this way a vacuum may be produced having a vapour pressure
of about the hundred-millionth of an atmosphere at 0° C. If, however,
some liquid mercury be left in the space in which the vacuum is
produced, and the containing part of the vessel be filled with liquid
air, the bright mirror of mercury which is deposited on the inside wall
of the bulb is still more effective than silver in protecting the
chamber from the influx of heat, owing to the high refractive index,
which involves great reflecting power, and the bad heat-conducting
powers of mercury.
[Illustration: FIG. 1.--Metallic Vacuum Vessel.]
With the discovery of the remarkable power of gas absorption possessed
by charcoal cooled to a low temperature (see below), it became possible
to make these vessels of metal. Previously this could not be done with
success, because gas occluded in the metal gradually escaped and
vitiated the vacuum; but now any stray gas may be absorbed by means of
charcoal so placed in a pocket within the vacuous space that it is
cooled by the liquid in the interior of the vessel. Metal vacuum
vessels (fig. 1), of a capacity of from 2 to 20 litres, may be formed of
brass, copper, nickel or tinned iron, with necks of some alloy that is a
bad conductor of heat, silvered glass vacuum cylinders being fitted as
stoppers. Such flasks, when properly constructed, have an efficiency
equal to that of the chemically-silvered glass vacuum vessels now
commonly used in low temperature investigations, and they are obviously
better adapted for transport. The principle of the Dewar vessel is
utilized in the Thermos flasks which are now extensively manufactured
and employed for keeping liquids warm in hospitals, &c.
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