Experimental Researches in Electricity, Volume 1Faraday, Michael
Science
Experimental Researches in Electricity, Volume 1
Faraday, Michael
Electricity; Electricity -- Early works to 1850
633. Clean platina, by which I mean such as has been made the positive pole
of a pile (570.), or has been treated with acid (605.), and has then been
put into distilled water for twelve or fifteen minutes, has a _peculiar
friction_ when one piece is rubbed against another. It wets freely with
pure water, even after it has been shaken and dried by the heat of a
spirit-lamp; and if made the pole of a voltaic pile in a dilute acid, it
evolves minute bubbles from every part of its surface. But platina in its
common state wants that peculiar friction: it will not wet freely with
water as the clean platina does; and when made the positive pole of a pile,
it for a time gives off large bubbles, which seem to cling or adhere to the
metal, and are evolved at distinct and separate points of the surface.
These appearances and effects, as well as its want of power on oxygen and
hydrogen, are the consequences, and the indications, of a soiled surface.
634. I found also that platina plates which had been cleaned perfectly soon
became soiled by mere exposure to the air; for after twenty-four hours they
no longer moistened freely with water, but the fluid ran up into portions,
leaving part of the surface bare, whilst other plates which had been
retained in water for the same time, when they were dried (580.) did
moisten, and gave the other indications of a clean surface.
635. Nor was this the case with platina or metals only, but also with
earthy bodies, Rock crystal and obsidian would not wet freely upon the
surface, but being moistened with strong oil of vitriol, then washed, and
left in distilled water to remove all the acid, they did freely become
moistened, whether they were previously dry or whether they were left wet;
but being dried and left exposed to the air for twenty-four hours, their
surface became so soiled that water would not then adhere freely to it, but
ran up into partial portions. Wiping with a cloth (even the cleanest) was
still worse than exposure to air; the surface either of the minerals or
metals immediately became as if it were slightly greasy. The floating upon
water of small particles of metals under ordinary circumstances is a
consequence of this kind of soiled surface. The extreme difficulty of
cleaning the surface of mercury when it has once been soiled or greased, is
due to the same cause.
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