Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances — John Shaqi
Experiments upon magnesia alba, Quicklime, and some other Alcaline SubstancesBlack, Joseph
Science
Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances
Black, Joseph
Alkalies; Carbon dioxide; Chemistry -- Early works to 1800; Phlogiston
We now perceive the reason, why crude and calcined _magnesia_, which
differ in many respects from one another, agree however in composing the
same kind of salt, when dissolved in any particular acid; for the crude
_magnesia_ seems to differ from the calcined chiefly by containing a
considerable quantity of air, which air is unavoidably dissipated and
lost during the dissolution.
From our experiments, it seems probable, that the increase of weight
which some metals acquire, by being first dissolved in acids, and then
separated from them again by alkalis, proceeds from air furnished by the
alkalis. And that in the _aurum fulminans_, which is prepared by the
same means, this air adheres to the gold in such a peculiar manner,
that, in a moderate degree of heat, the whole of it recovers its
elasticity in the same instant of time; and thus, by the violent shock
which it gives to the air around, produces the loud crack or fulmination
of this powder. Those who will imagine the explosion of such a minute
portion of fixed air, as can reside in the _aurum fulminans_, to be
insufficient for the excessive loudness of the noise, will consider,
that it is not a large quantity of motion communicated to the air, but
rather a smart stroke which produces sound, and that the explosion of
but a few particles of fixed air may be capable of causing a loud noise,
provided they all recover their spring suddenly, and in the same
instant.
The above experiments lead us also to conclude, that volatile alkalis,
and the common absorbent earths, which lose their air by being joined to
acids, but shew evident signs of their having recovered it, when
separated from them by alkalis, received it from these alkalis which
lost it in the instant of their joining with the acid.
The following are a few experiments upon three of the absorbent earths,
made in order to compare them with one another, and with _magnesia_.
Suspecting that _magnesia_ might possibly be no other than a common
calcarious earth, which had changed its nature, by having been
previously combined with an acid, I saturated a small quantity of chalk
with the muriatic acid, separated the acid from it again by means of a
fixed alkali, and carefully washed away the whole of the salt.
The chalk when dryed was not found to have suffered any alteration; for
it effervesced with the vitriolic acid, but did not dissolve in it; and
when exposed to a violent fire, was converted into a quick-lime, in all
respects similar to that obtained from common chalk.
In another experiment of the same kind, I used the vitriolic acid with
the same event.
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