Experiments upon magnesia alba, Quicklime, and some other Alcaline SubstancesBlack, Joseph
Science
Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances
Black, Joseph
Alkalies; Carbon dioxide; Chemistry -- Early works to 1800; Phlogiston
Any calcarious matter reduced to a fine powder, and thrown into a warm
solution of alum, immediately raises a brisk effervescence. But the
powder is not dissolved; it is rather increased in bulk: and if the
addition be repeated until it is no longer accompanied with
effervescence, the liquor loses all taste of the alum, and yields only a
very light cloud upon the admixture of an alkali.
From this experiment we learn, that acids attract the calcarious earths
more strongly than they do the earth of alum; and as the acid in this
salt is exactly the same with the vitriolic, it composes with the
calcarious earth a neutral substance, which is very difficultly soluble
in water, and therefore falls down to the bottom of the vessel along
with the earth of alum which is deprived of its acid. The light cloud
formed by the alkali proceeds from the minute portion of the calcarious
compound which saturates the water.
The earth of animal bones, when reduced to a fine powder and thrown into
a diluted vitriolic acid, gradually absorbs the acid in the same manner
as the calcarious earths, but without any remarkable effervescence. When
it is added to the nitrous or to the muriatic acid, it is slowly
dissolved. The compound liquor thence produced is extremely acrid, and
still changes the colour of the juice of violets to a red, even after it
is fully saturated with the absorbent. Distilled vinegar has little or
no effect upon this earth; for after a long digestion it still retains
its sour taste, and gives only a light cloud upon the addition of an
alkali.
By dropping a dissolved fixed alkali into a warm solution of alum, I
obtained the earth of this salt, which, after being well washed and
dried, was found to have the following properties.
It is dissolved in every acid but very slowly, unless assisted by heat.
The several solutions, when thoroughly saturated, are all astringent
with a slight degree of an acid taste, and they also agree with a
solution of alum in this, that they give a red colour to the infusion of
turnsol.
Neither this earth, nor that of animal bones, can be converted into
quick-lime by the strongest fire, nor do they suffer any change worth
notice. Both of them seem to attract acids but weakly, and to alter
their properties less when united to them than the other absorbents.
PART II.
In reflecting afterwards upon these experiments, an explication of the
nature of lime offered itself, which seemed to account, in an easy
manner, for most of the properties of that substance.
It is sufficiently clear, that the calcarious earths in their native
state, and that the alkalis and magnesia in their ordinary condition,
contain a large quantity of fixed air, and this air certainly adheres to
them with considerable force, since a strong fire is necessary to
separate it from magnesia, and the strongest is not sufficient to expel
it entirely from fixed alkalis, or take away their power of effervescing
with acid salts.
Public-domain text, read in full here on John Shaqi.
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