Experiments upon magnesia alba, Quicklime, and some other Alcaline SubstancesBlack, Joseph
Science
Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances
Black, Joseph
Alkalies; Carbon dioxide; Chemistry -- Early works to 1800; Phlogiston
We must therefore acknowledge a stronger attraction between the
calcarious earths and acids than between these and magnesia: but how
does it then happen, that, if magnesia saturated with air be mixed with
a compound of acid and calcarious earth, these two last, which attract
one another the most strongly, do not remain united; but the acid is
joined to the magnesia, and the calcarious earth to the air which it
attracts much more weakly than it does the acid? Is it because the sum
of the forces which tend to join the magnesia to the acid and the
calcarious earth to the air, is greater than the sum of the forces which
tend to join the calcarious earth to the acid, and the magnesia to the
air: and because there is a repulsion between the acid and air, and
between the two earths; or they are somehow kept asunder in such a
manner as hinders any three of them from being united together?
The first part of this supposition is favoured by our experiments, which
seem to shew a greater difference between the forces wherewith the
calcarious earth and magnesia attract fixed air, than between those
which dispose them to unite with the acid. The repulsions however hinted
in the second are perhaps more doubtful, tho' they are suggested in many
other instances of decomposition; but the bounds of my present purpose
will not allow me to enter upon this subject, which is one of the most
extensive in chemistry.
We meet also with a difficulty with respect to the volatile alkali
similar to the above. Thus a calcarious earth that is pure or free of
air has a much stronger attraction for acids than a pure volatile
alkali, as is evident when we mix quick-lime with salt ammoniac; for the
alkali is then immediately detached from the acid: and agreeably to this
I found, upon trial, that a pure or caustic volatile alkali does not
separate a calcarious earth from an acid. Yet, if we mix a mild volatile
alkali, which is a compound of alkali and air, with a compound of acid
and calcarious earth, these two last, which attract one another most
strongly, do not remain united; but the acid is joined to the alkali and
the earth to the air, as happens in the precipitation of a calcarious
earth from an acid, by means of the common or mild volatile alkali.
Public-domain text, read in full here on John Shaqi.
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