Experiments upon magnesia alba, Quicklime, and some other Alcaline SubstancesBlack, Joseph
Science
Experiments upon magnesia alba, Quicklime, and some other Alcaline Substances
Black, Joseph
Alkalies; Carbon dioxide; Chemistry -- Early works to 1800; Phlogiston
Twenty four grains of magnesia in fine powder were mixed with five
ounces of the caustic ley in a small vial, which was immediately corked
and shaken frequently for four hours. The ley was then poured off, and
the magnesia washed with repeated affusions of water, and dried. It had
lost about the half of its weight, and when reduced to a fine powder was
readily dissolved by acids with an effervescence which was hardly
perceivable: the alkali had therefore extracted its air. I also threw
some fresh magnesia into the ley which had been poured off, and thereby
rendered it perfectly mild and similar to a solution of salt of tartar;
so that it effervesced briskly with acids.
With an ounce of the mild spirit of salt ammoniac, I mixed a dram of
magnesia in very fine powder which had been previously deprived of its
air by fire; and observing that the magnesia had a tendency to concrete
into a solid mass, I shook the vial very frequently. After some days the
powder was increased to more than double its former bulk; and when the
vial was opened, the alkaline spirit emitted a most intolerably pungent
smell. It likewise floated upon water, but was not perfectly caustic;
for it still yielded some air when mixed with acids, and also rendered
lime-water turbid: neither of which would probably have happened if I
had used a greater quantity of magnesia, or had allowed the mixture to
remain a longer time in the vial. I now washed out the whole of the
mixture into a bowl, and dryed the magnesia until it lost all smell of
the alkali. It weighed a dram and fifty eight grains, effervesced
violently with acids, and therefore contained a large quantity of air,
which had been drawn from the alkali by a stronger attraction.
Having formerly shewn, that magnesia saturated with air separates an
acid from a calcarious earth, which it is not able to do after being
deprived of its air by fire; I now suspected that the air was the cause
of this separation, because I found that it was joined to the calcarious
earth at the same time that the acid was joined to the earth of
magnesia; and imagined that a pure calcarious earth might possibly have
a stronger attraction for acids than a earth of magnesia.
I therefore dissolved two drams of magnesia in the marine acid, and
thus obtained a compound of an acid and of the pure earth of this
substance; for the air which was at first attached to it, was expelled
during the dissolution. I then added thirty grains of strong quick-lime
in exceeding fine powder, shook the mixture well, and filtrated it. The
powder remaining in the paper, after being well washed, was found to be
a magnesia, which, as I expected, was destitute of air; for it was
dissolved by the vitriolic acid without effervescence. And the filtrated
liquor contained the lime united to the acid; for upon dropping spirit
of vitriol into it, a white powder was immediately formed.
Public-domain text, read in full here on John Shaqi.
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