Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and AgricultureLiebig, Justus, Freiherr von
Science
Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and Agriculture
Liebig, Justus, Freiherr von
Chemistry
That hypothesis, however, has shared the fate of innumerable
imaginative explanations of natural phenomena, in which our
predecessors indulged. They have now no advocate. The force of
truth, dependent upon observation, is irresistible. A great many
substances have been discovered amongst organic bodies, composed of
the same elements in the same relative proportions, and yet
exhibiting physical and chemical properties perfectly distinct one
from another. To such substances the term Isomeric (from 1/ao1/
equal and aei1/o1/ part) is applied. A great class of bodies, known
as the volatile oils, oil of turpentine, essence of lemons, oil of
balsam of copaiba, oil of rosemary, oil of juniper, and many others,
differing widely from each other in their odour, in their medicinal
effects, in their boiling point, in their specific gravity, &c., are
exactly identical in composition,--they contain the same elements,
carbon and hydrogen, in the same proportions.
How admirably simple does the chemistry of organic nature present
itself to us from this point of view! An extraordinary variety of
compound bodies produced with equal weights of two elements! and how
wide their dissimilarity! The crystallised part of the oil of roses,
the delicious fragrance of which is so well known, a solid at
ordinary temperatures, although readily volatile, is a compound body
containing exactly the same elements, and in the same proportions,
as the gas we employ for lighting our streets; and, in short, the
same elements, in the same relative quantities, are found in a dozen
other compounds, all differing essentially in their physical and
chemical properties.
These remarkable truths, so highly important in their applications,
were not received and admitted as sufficiently established, without
abundant proofs. Many examples have long been known where the
analysis of two different bodies gave the same composition; but such
cases were regarded as doubtful: at any rate, they were isolated
observations, homeless in the realms of science: until, at length,
examples were discovered of two or more bodies whose absolute
identity of composition, with totally distinct properties, could be
demonstrated in a more obvious and conclusive manner than by mere
analysis; that is, they can be converted and reconverted into each
other without addition and without subtraction.
In cyanuric acid, hydrated cyanic acid, and cyamelide, we have three
such isomeric compounds.
Cyanuric acid is crystalline, soluble in water, and capable of
forming salts with metallic oxides.
Hydrated cyanic acid is a volatile and highly blistering fluid,
which cannot be brought into contact with water without being
instantaneously decomposed.
Cyamelide is a white substance very like porcelain, absolutely
insoluble in water.
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