Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and AgricultureLiebig, Justus, Freiherr von
Science
Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and Agriculture
Liebig, Justus, Freiherr von
Chemistry
Now if we place the first,--cyanuric acid,--in a vessel hermetically
sealed, and apply a high degree of heat, it is converted by its
influence into hydrated cyanic acid; and, then, if this is kept for
some time at the common temperature, it passes into cyamelide, no
other element being present. And, again inversely, cyamelide can be
converted into cyanuric acid and hydrated cyanic acid.
We have three other bodies which pass through similar changes, in
aldehyde, metaldehyde, and etaldehyde; and, again two, in urea and
cyanuret of ammonia. Further, 100 parts of aldehyde hydrated butyric
acid and acetic ether contain the same elements in the same
proportion. Thus one substance may be converted into another without
addition or subtraction, and without the participation of any
foreign bodies in the change.
The doctrine that matter is not infinitely divisible, but on the
contrary, consists of atoms incapable of further division, alone
furnishes us with a satisfactory explanation of these phenomena. In
chemical combinations, the ultimate atoms of bodies do not penetrate
each other, they are only arranged side by side in a certain order,
and the properties of the compound depend entirely upon this order.
If they are made to change their place--their mode of arrangement--by
an impulse from without, they combine again in a different manner,
and another compound is formed with totally different properties. We
may suppose that one atom combines with one atom of another element
to form a compound atom, while in other bodies two and two, four and
four, eight and eight, are united; so that in all such compounds the
amount per cent. of the elements is absolutely equal; and yet their
physical and chemical properties must be totally different, the
constitution of each atom being peculiar, in one body consisting of
two, in another of four, in a third of eight, and in a fourth of
sixteen simple atoms.
The discovery of these facts immediately led to many most beautiful
and interesting results; they furnished us with a satisfactory
explanation of observations which were before veiled in mystery,--a
key to many of Nature's most curious recesses.
Again; solid bodies, whether simple or compound, are capable of
existing in two states, which are known by the terms amorphous and
crystalline.
When matter is passing from a gaseous or liquid state slowly into a
solid, an incessant motion is observed, as if the molecules were
minute magnets; they are seen to repel each other in one direction,
and to attract and cohere together in another, and in the end become
arranged into a regular form, which under equal circumstances is
always the same for any given kind of matter; that is, crystals are
formed.
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