Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and AgricultureLiebig, Justus, Freiherr von
Science
Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and Agriculture
Liebig, Justus, Freiherr von
Chemistry
Among the elements are several instances of remarkable similarity of
properties. Thus there is a strong resemblance between platinum and
iridium; bromine and iodine; iron, manganese, and magnesium; cobalt
and nickel; phosphorus and arsenic; but this resemblance consists
mainly in their forming isomorphous compounds in which these
elements exist in the same relative proportion. These compounds are
similar, because the atoms of which they are composed are arranged
in the same manner. The converse of this is also true: nitrate of
strontia becomes quite dissimilar to its common state if a certain
proportion of water is taken into its composition.
If we suppose selenium to be merely modified sulphur, and phosphorus
modified arsenic, how does it happen, we must inquire, that
sulphuric acid and selenic acid, phosphoric and arsenic acid,
respectively form compounds which it is impossible to distinguish by
their form and solubility? Were these merely isomeric, they ought to
exhibit properties quite dissimilar!
We have not, I believe, at present the remotest ground to suppose
that any one of those substances which chemists regard as elements
can be converted into another. Such a conversion, indeed, would
presuppose that the element was composed of two or more ingredients,
and was in fact not an element; and until the decomposition of these
bodies is accomplished, and their constituents discovered, all
pretensions to such conversions deserve no notice.
Dr. Brown of Edinburgh thought he had converted iron into rhodium,
and carbon or paracyanogen into silicon. His paper upon this subject
was published in the Transactions of the Royal Society of Edinburgh,
and contained internal evidence, without a repetition of his
experiments, that he was totally unacquainted with the principles of
chemical analysis. But his experiments have been carefully repeated
by qualified persons, and they have completely proved his ignorance:
his rhodium is iron, and his silicon an impure incombustible coal.
LETTER VI
My dear Sir,
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