Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and AgricultureLiebig, Justus, Freiherr von
Science
Familiar Letters on Chemistry, and Its Relation to Commerce, Physiology, and Agriculture
Liebig, Justus, Freiherr von
Chemistry
Time and freedom of motion for the particles of bodies are necessary
to the formation of crystals. If we force a fluid or a gas to become
suddenly solid, leaving no time for its particles to arrange
themselves, and cohere in that direction in which the cohesive
attraction is strongest, no crystals will be formed, but the
resulting solid will have a different colour, a different degree of
hardness and cohesion, and will refract light differently; in one
word, will be amorphous. Thus we have cinnabar as a red and a
jet-black substance; sulphur a fixed and brittle body, and soft,
semitransparent, and ductile; glass as a milk-white opaque
substance, so hard that it strikes fire with steel, and in its
ordinary and well-known state. These dissimilar states and
properties of the same body are occasioned in one case by a regular,
in the other by an irregular, arrangement of its atoms; one is
crystalline, the other amorphous.
Applying these facts to natural productions, we have reason to
believe that clay-slate, and many kinds of greywacke, are amorphous
feldspar, as transition limestone is amorphous marble, basalt and
lava mixtures of amorphous zeolite and augite. Anything that
influences the cohesion, must also in a certain degree alter the
properties of bodies. Carbonate of lime, if crystallised at ordinary
temperatures, possesses the crystalline form, hardness, and
refracting power of common spar; if crystallised at a higher
temperature, it has the form and properties of arragonite.
Finally, Isomorphism, or the equality of form of many chemical
compounds having a different composition, tends to prove that matter
consists of atoms the mere arrangement of which produces all the
properties of bodies. But when we find that a different arrangement
of the same elements gives rise to various physical and chemical
properties, and a similar arrangement of different elements produces
properties very much the same, may we not inquire whether some of
those bodies which we regard as elements may not be merely
modifications of the same substance?--whether they are not the same
matter in a different state of arrangement? We know in fact the
existence of iron in two states, so dissimilar, that in the one, it
is to the electric chain like platinum, and in the other it is like
zinc; so that powerful galvanic machines have been constructed of
this one metal.
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