Faraday, Michael, 1791-1867; Physicists -- Great Britain -- Biography
On May 23, 1833, he read a paper before the Royal Society 'On a new
Law of Electric Conduction.' He found that, though the current passed
through water, it did not pass through ice:--why not, since they are
one and the same substance? Some years subsequently he answered this
question by saying that the liquid condition enables the molecule
of water to turn round so as to place itself in the proper line of
polarization, while the rigidity of the solid condition prevents this
arrangement. This polar arrangement must precede decomposition, and
decomposition is an accompaniment of conduction. He then passed on to
other substances; to oxides and chlorides, and iodides, and salts, and
sulphurets, and found them all insulators when solid, and conductors
when fused. In all cases, moreover, except one--and this exception he
thought might be apparent only--he found the passage of the current
across the fused compound to be accompanied by its decomposition. Is
then the act of decomposition essential to the act of conduction in
these bodies? Even recently this question was warmly contested. Faraday
was very cautious latterly in expressing himself upon this subject;
but as a matter of fact he held that an infinitesimal quantity of
electricity might pass through a compound liquid without producing its
decomposition. De la Rive, who has been a great worker on the chemical
phenomena of the pile, is very emphatic on the other side. Experiment,
according to him and others, establishes in the most conclusive manner
that no trace of electricity can pass through a liquid compound without
producing its equivalent decomposition.[2]
Public-domain text, read in full here on John Shaqi.
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