Faraday, Michael, 1791-1867; Physicists -- Great Britain -- Biography
Faraday has now got fairly entangled amid the chemical phenomena of the
pile, and here his previous training under Davy must have been of the
most important service to him. Why, he asks, should decomposition thus
take place?--what force is it that wrenches the locked constituents
of these compounds asunder? On the 20th of June, 1833, he read a paper
before the Royal Society 'On Electro-chemical Decomposition,' in which
he seeks to answer these questions. The notion had been entertained
that the poles, as they are called, of the decomposing cell, or in other
words the surfaces by which the current enters and quits the liquid,
exercised electric attractions upon the constituents of the liquid and
tore them asunder. Faraday combats this notion with extreme vigour.
Litmus reveals, as you know, the action of an acid by turning red,
turmeric reveals the action of an alkali by turning brown. Sulphate of
soda, you know, is a salt compounded of the alkali soda and sulphuric
acid. The voltaic current passing through a solution of this salt
so decomposes it, that sulphuric acid appears at one pole of the
decomposing cell and alkali at the other. Faraday steeped a piece of
litmus paper and a piece of turmeric paper in a solution of sulphate of
soda: placing each of them upon a separate plate of glass, he connected
them together by means of a string moistened with the same solution.
He then attached one of them to the positive conductor of an electric
machine, and the other to the gas-pipes of this building. These he
called his 'discharging train.' On turning the machine the electricity
passed from paper to paper through the string, which might be varied in
length from a few inches to seventy feet without changing the result.
The first paper was reddened, declaring the presence of sulphuric acid;
the second was browned, declaring the presence of the alkali soda. The
dissolved salt, therefore, arranged in this fashion, was decomposed by
the machine, exactly as it would have been by the voltaic current.
When instead of using the positive conductor he used the negative,
the positions of the acid and alkali were reversed. Thus he satisfied
himself that chemical decomposition by the machine is obedient to the
laws which rule decomposition by the pile.
Public-domain text, read in full here on John Shaqi.
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