Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
"Gallic acid was discovered by Scheele in 1786,
and exists ready formed in the bark of many trees,
and in gall-nuts. It is always associated with
tannin, a substance to which it is allied in a manner
hitherto unexplained. It is distinguished from
tannin by causing no precipitate in a solution of
gelatine. With a salt of iron it forms a dark blue
coloured compound, which is the basis of ink. The
finest colour is procured when the peroxide and
protoxide of iron are mixed together. This character
distinguishes gallic acid from every other substance
excepting tannin."
The general lack of information or knowledge respecting
ink chemistry or its time-phenomena was not
confined to any particular country, and it does not
appear that any general or specific attention was
scientifically directed to it until 1765, when William
Lewis, F. R. S., an English chemist, publicly announced
that he proposed to investigate the subject.
His experimentations covered a period of many years
and their results and his theories as to the phenomena
of inks were published in 1797. The most valuable
of his conclusions were that an excess of iron salt in
the ink is detrimental to color permanence (such ink
becoming brown on exposure) and also that acetic
acid in the menstruum provides an ink of greater
body and blackness than sulphuric acid does (a circumstance
due to the smaller resistance of acetic acid
to the formation of iron gallo-tannate). Many of his
other observations were later shown to have been
erroneous. Dr. Lewis was the first to advocate log-
wood as a tinctorial agent in connection with iron and
gall compositions.
Ribaucourt, a French ink maker, in 1798 determined
that an excess of galls is quite as injurious to
the permanence of ink as an excess of iron.
Pending the completion of the researches of Lewis,
the Royal Society of England, affected by complaints
from all quarters relative to the inferiority of inks as
compared with those of earlier times, brought the
subject to the attention of many of its members for
discussion and advice. Its secretary, Charles Blagden,
M. D., read a paper before the society, June 28, 1787,
which was published in the "Philosophical Transactions"
and widely circulated. It is so interesting that
copious extracts are given:
Public-domain text, read in full here on John Shaqi.
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