Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.Carvalho, David Nunes
History
Forty Centuries of Ink: Or, A chronological narrative concerning ink and its backgrounds, introducing incidental observations and deductions, parallels of time and color phenomena, bibliography, chemistry, poetical effusions, citations, anecdotes and curiosa together with some evidence respecting the evanescent character of most inks of to-day and an epitome of chemico-legal ink.
Carvalho, David Nunes
Ink
"Whilst I was considering of the experiments
to be made, in order to ascertain the composition
of ancient inks, it occurred to me that perhaps one
of the best methods of restoring legibility to decayed
writing might be to join phlogisticated alkali
with the remaining calx of iron, because, as the
quantity of precipitate formed by these two substances
very much exceeds that of the iron alone,
the bulk of the colouring matter would thereby be
greatly augmented. M. Bergman was of opinion
that the blue precipitate contains only between a
fifth and a sixth part of its weight of iron, and
though subsequent experiments tend to show that,
in some cases at least, the proportion of iron is
much greater, yet upon the whole it is certainly
true, that if the iron left by the stroke of a pen
were joined to the colouring matter of phlogisticated
alkali, the quantity of Prussian blue thence
resulting would be much greater than the quantity
of black matter originally contained in the ink
deposited by the pen, though perhaps the body of
colour might not be equally augmented. To bring
the idea to the test, I made a few experiments as
follows:
"The phlogisticated alkali was rubbed upon the
bare writing in different quantities, but in general
with little effect. In a few instances, however, it
gave a bluish tinge to the letters, and increased
their intensity, probably where something of an
acid nature had contributed to the diminution of
their colour.
"Reflecting that when phlogisticated alkali forms
its blue precipitate with iron the metal is first usually
dissolved in an acid, I was next induced to try the
effect of adding a dilute mineral acid to writing besides
the alkali. This answered fully to my expectations,
the letters changing very speedily to a deep
blue colour, of great beauty and intensity.
"It seems of little consequence as to the strength
of colour obtained, whether the writing be first wetted
with the acid, and then the phlogisticated alkali be
touched upon it, or whether the process be inverted,
beginning with the alkali; but on another account
I think the latter way preferable. For the principal
inconvenience which occurs in the proposed
method of restoring MSS. is, that the colour frequently
spreads, and so much blots the parchment
as to detract greatly from the legibility; now this
appears to happen in a less degree when the alkali
is put on first, and the dilute acid is added upon it.
Public-domain text, read in full here on John Shaqi.
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