Gems in the Smithsonian InstitutionDesautels, Paul E.
History
Gems in the Smithsonian Institution
Desautels, Paul E.
Gems; Precious stones; Smithsonian Institution
Gems have the ability to separate “white light” (the mixture of all
colors) into its various colors, producing flashes of red, yellow,
green, and other colors. Separation occurs because the various colors,
or wavelengths composing white light passing through the gem, are each
bent or refracted a different amount. Red is bent least, followed in
order by orange, yellow, green, blue, and violet, which is bent most.
This characteristic of being able to produce flashes of color, as seen
prominently in diamond, is known as _dispersion_ or _fire_. Quartz and
glass have low dispersion, and hence they make poor diamond substitutes.
Some of the newer synthetic gemstones, such as titania, have extremely
high dispersion, with resulting fire. Zircon, a natural gemstone of
suitable hardness, exhibits high dispersion and is a commonly used
substitute for diamond.
CHEMICAL CHARACTERISTICS OF GEMSTONES
Since gems are embraced in the mineral kingdom, and minerals are
naturally occurring chemical substances, it follows that all the
accepted terms of chemical description can be applied to them. When a
chemist learns that ruby is an impure aluminum oxide, he understands a
great deal about the nature, origin, and behavior of ruby. He can assign
to it the chemical formula Al₂O₃, symbolizing its basic composition as
two atoms of aluminum united with three of oxygen. Similarly, other
popular gemstones can be described chemically as follows:
Diamond Carbon C
Sapphire Aluminum oxide Al₂O₃
Quartz Silicon dioxide SiO₂
Emerald Beryllium aluminum silicate Be₃Al₂(SiO₃)₆
Spinel Magnesium aluminate Mg(AlO₂)₂
Significantly, ruby and sapphire are chemically identical, both being of
the mineral species corundum. As already explained, the difference in
color is due entirely to very slight traces of chemical impurities.
Frequently, the impurities are present in irregular patches that give
spotty color effects.
Some mineral species possess many of the desirable qualities of
gemstones yet cannot be used as gems because they are chemically active
and therefore are less durable. They undergo alteration and
decomposition when exposed to light or to one or another of such
substances as air, water, skin acids and oils.
3
THE SHAPING OF GEMSTONES
Gemstone crystals often have naturally brilliant, reflecting faces, but
rarely are they perfect and unblemished. Also, their natural shapes do
not provide the best expression of their luster, brilliance, dispersion,
color, and other inherent properties. In fashioning a gemstone, the
skilled artisan tries to develop these hidden assets and to otherwise
enhance the gemstone’s general beauty.
Public-domain text, read in full here on John Shaqi.
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