The metals produced in covered pots are usually softer and contain more
lead and fluxes than those produced in open pots. In using open pots the
heat of the furnace has direct access to the surface of the metal
therein. In the case of covered pots, the heat has to be conducted
through the cover of the pot, which retards the heat to a certain
extent. On this account, softer mixtures are used in covered pots.
------------------------------------------------------------------------
CHAPTER V
COLOURED GLASS AND ARTIFICIAL GEMS
In colouring glass, either or several of the following colorific oxides
may be used. They are added to the batch before fusion. Varying
proportions are added, according to the depth of the colour desired.
Occasionally the colour is influenced by the nature and composition of
the rest of the batch. In some instances several colouring oxides are
used. In this way many delicate tints are obtained; in fact, there are
but few colours that cannot be produced in glass.
=For Green Glasses= the following oxides may be used: Chromium oxide, 2
to 6 per cent. of the batch; black oxide of copper, ·5 to 3 per cent.;
red iron oxide, ·5 to 1 per cent.; or a mixture of two or three of the
above oxides in less proportions. Salts of chromium, copper, or iron may
be used as the carbonates, sulphates, and chromates.
=For Blue Glasses=, cobalt oxide, ·1 to 1 per cent. of the batch; zaffre
blue or smalts, 1 to 3 per cent.; nickel oxide, 2 to 4 per cent.; iron
oxide, 1 to 2 per cent.; black oxide of copper, 2 per cent.
=For Violet and Purple=, manganese oxide, 2 to 4 per cent. of the batch.
=For Rubies=, red oxide of copper, gold chloride, purple of cassius,
antimony oxysulphide, selenium metal in small proportions.
=For Yellows=, uranium yellow, 4 to 6 per cent. of the batch; potassium
antimoniate, 10 per cent.; carbon, 6 per cent.; sulphur, 5 per cent.;
ferric oxide, 2 to 4 per cent. Silver nitrate and cadmium sulphide are
also used.
=Black Glass= is obtained from mixtures of cobalt oxide, nickel oxide,
iron oxide, platinum and iridium. Many very dark or black bottle glasses
are obtained by using basalt, iron ores, or greenstone in a powdered
form, added to the batch ingredients.
=White Glasses= or =Opal= are obtained by using phosphate of lime, talc,
cryolite, alumina, zinc oxide, calcium fluoride, either singly or in
double replacements of the bases present in the glass batches.
Many of the colouring oxides give distinctive colours to glass of
different compositions; also the resulting colours may vary with the
same colouring ingredient, according to reducing or oxidising meltings.
Thus, in a batch of reducing composition, red copper oxide gives ruby
glass, but in oxidising compositions the colour given is green or
bluish-green. Iron oxide in an oxidising batch gives a yellow. In the
reducing batch it gives bluish or green results. Manganese is similarly
affected.
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