=Carbonate of Barium=, or =Witherite=, is a very heavy, white powder,
and is a form of earthy base available for use in glassmaking. It can be
used to replace lime, with similar results. By replacing other elements
in the glass which are of lower density, barium can be used to increase
the density of glass. Like lime it is a very powerful flux in glass at
high temperatures. It gives increased brilliancy and little coloration.
For this reason it is very useful in the manufacture of pressed
glassware, giving a glass which leaves the moulds with better gloss than
is found to be the case with lime glasses.
=Magnesia= and =Strontia= are other bases which are less used in
glassmaking.
=Zinc Oxide= is a base used in the manufacture of many optical glasses.
With boric acid it gives silicates of a low coefficient of expansion and
special optical values. Used with cryolite, it forms a very dense opal
suitable for pressed ware. It is rather more expensive than the other
bases used.
=Cryolite= is a natural opacifying ingredient used in making opal
glasses. It consists of a combination of the fluorides of aluminium and
sodium, and is one of the most active fluxes known to glass and enamel
makers. Its cutting chemical attack on the pots is very intensive. It is
imported from Greenland. An artificially manufactured form of cryolite
is known, which is a little cheaper than the natural variety and gives
similar results in opacifying glass.
=Alumina.= This is sometimes present to a small extent in glass makers’
sands. As such it is not a dangerous impurity. It exists in combination
with silica and potash to a large extent in feldspars, china clays, and
granites. Alumina, when used, has a decided influence upon the viscosity
and permanency of glass. In large proportions it noticeably diminishes
the fusibility of glass, and makes it more or less translucent. Owing to
the refractory nature of alumina it is with difficulty that it can be
diffused in alkaline silicates, borates, or lead silicates; consequently
any considerable proportion present in glass may cause cords or striae,
which are objectionable defects in the glass.
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