=Sodium Nitrate=, or =Chili Nitre=, is the corresponding soda salt to
potash nitre. It is much cheaper, but less pure; it has a similar but
not nearly so powerful an oxidising action in the glass as potash nitre.
It is exported from Chili, where it exists naturally in a crude state as
“Caliche,” from which the nitrate is refined by recrystallisation.
=Boric Acid= acts as an acid in glass, as does silicic acid. It renders
glass more fusible and brilliant; it has a searching action upon the
colourising properties of certain metallic oxides when they are
dissolved in the glass. It is an expensive ingredient, but is
considerably used in optical and special chemical glassware in replacing
a portion of the silicates ordinarily used and forming borates. It
cannot be used in large amounts, as an excess produces glass of a less
stable nature.
=Borax=, or =Borate of Soda=, consists of boric acid combined with soda.
It is a very useful glassmaking material and is an active fluxing agent.
If used in excess in glass mixtures it causes considerable ebullition,
or boiling of the metal. In moderate proportions it is used in the
manufacture of enamels for glass, as it helps to dissolve the colorific
oxides and diffuse the colouring throughout the enamel mass.
=Tincal=, and =Borate of Lime=, are other forms in which borates may be
introduced into glass.
=Carbonate of Lime=, =Limespar=, =Limestone=, =Paris White=, or
=Whitening= are all forms of =Calcium Carbonate=. It is an earthy base
and is added to the simple alkaline silicates and borates to form
insoluble combinations or double silicates of soda and lime. By the use
of lime, glasses are rendered more permanent and unchangeable when in
use. Lime forms a very powerful flux at high temperatures. The quantity
used must be carefully regulated according to the proportion of other
bases present; otherwise an inferior or less stable glass may be
produced. In excess it causes glass to assume a devitrified state.
=Dolomite= is a _Magnesium Limestone_, and is a natural stone which is
available for use in making glass in tank furnaces.
=Fluorspar=, or =Fluoride of Lime=, is used in giving opacity and
translucency to glass. It can only be used in small amounts, as the
presence of any large proportion attacks the clay of the pots, causing
serious damage by the sharp cutting chemical action due to the evolution
of fluorine gas.
=Phosphate of Lime= is another material which produces opacity and
translucency, but does not seriously attack the pots. Bone ash is a form
of phosphate of lime, and is procured by calcining bones until all
organic matter is consumed.
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