While the range of bodies that can be obtained in the vitreous state
is very large, only a comparatively small number of substances are
ordinarily incorporated in industrial glasses. With the exception of
certain special glasses used for scientific purposes, such as the
construction of optical lenses, thermometers and vessels intended to
resist unusual treatment, all industrial glasses are of the nature
of mixed silicates of a few bases, viz., the alkalies, sodium and
potassium, the alkaline earths, calcium, magnesium, strontium, and
barium, the oxides of iron and aluminium (generally present in minor
quantities), and lead oxide. The manner in which these various elements
enter into combination and solution with one another has been much
investigated, and the more general conclusions have been anticipated
in what has been said above. It is abundantly evident that glasses
are not definite chemical compounds, but rather solutions, in varying
proportions, of a series of definite compounds in one another. In many
cases the actual constitution of industrial glasses is so complex as,
for the present at all events, to baffle adequate chemical expression.
One of the factors that limit the range of possible compositions
of glasses has already been indicated, and two others must now be
discussed. For industrial purposes, the cost and rarity of the
ingredients becomes a vital bar at a certain stage; thus the use of
such elements as lithium, thallium, etc., is prohibitively costly. In
another direction the glass-maker is very effectively restrained by
the limitations of his furnaces as regards temperature. The presence
of excessive proportions of silica, lime, alumina, etc., tends to
raise the temperature required for the free fusion of the glass, and
when this temperature seriously exceeds 1600° C., the manufacture of
the glass in ordinary furnaces becomes impossible. Thus pure silica
can be converted into a glass possessing very valuable properties, but
the requisite temperature cannot be attained in regenerative gas-fired
furnaces such as are ordinarily used by glass manufacturers. The
production of this glass has accordingly been carried on upon a small
scale only by means of laboratory furnaces heated by oxy-acetylene
flames, while latterly a less perfect variety of silica glass-ware
has been produced on a large scale by the aid of electric furnaces.
Such methods are, however, obviously limited to very special products
commanding special prices.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account