A further limitation in the choice of chemical components is placed
upon the manufacturer by the actual chemical behaviour of the glass
both during manufacture and in use. As regards chemical behaviour
during manufacture, it must be borne in mind that, although glasses
are of the nature of solutions rather than of compounds, yet these
solutions tend towards a state of saturation; thus a glass rich in
silica and deficient in bases will readily dissolve any basic materials
with which it may come in contact, while, on the other hand, a glass
rich in bases and poor in acid constituents such as silica, boric acid
or alumina, will readily absorb acid bodies from its surroundings.
During the process of melting, glass is universally contained in
fire-clay vessels. These are chosen, as regards their own chemical
composition, so as to offer to the molten glass a few of those
materials in which the glass itself is deficient; yet a limit arises in
this respect also, since glasses very rich in bases, such as the very
dense lead and barium glass made for optical purposes, rapidly attack
any fire-clay with which they may come in contact. The finished glass
also betrays its chemical composition by its chemical behaviour towards
the atmospheric agents, such as moisture and carbonic acid, with which
it comes in contact; glasses containing an excessive proportion of
alkali, for example, are found to be seriously hygroscopic and to
undergo rapid decomposition, especially in a damp atmosphere.
Within the limits set by these considerations, the glass manufacturer
chooses the chemical composition of his glass according to the purpose
for which it is intended; for most industrial products the cheapest and
most accessible raw materials that will yield a glass of the requisite
appearance are employed, while for special purposes the dependence of
physical properties upon chemical composition is utilised, as far as
possible, in order to attain a glass specially suited to the particular
requirements in question. Thus the flint and barium glasses used for
table and ornamental ware derive from the dense and strongly refracting
oxides of lead and barium their properties of brilliancy and weight.
The fusibility and softness imparted to the glass by the presence
of these bases further adapts it to its purpose by facilitating the
complicated manipulations to which the glass must be subjected in the
manufacturing processes.
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