the best example, the colouring substance, be it gold or cuprous oxide,
is present in the form of minute but by no means atomic or molecular
particles suspended in the glass. The presence of these particles has
been made optically evident, although it can hardly be said that they
have been rendered visible, and it is at all events probable that these
suspended particles act each as a whole in absorbing the light-waves
characteristic of the colour which they produce in glass. This being
the case, it is easy to understand how readily the colour of such
glasses is altered or spoilt by manipulations which involve heating
and cooling at different rates--too rapid a rate of cooling producing
a different grouping of the minute particles, altering their size or
shape, or even obliterating them entirely by allowing the element in
question to go into or to remain in solution in the glass.
While it would be entirely foreign to the purpose of this volume to
give in this place a series of recipes for the production of various
kinds of coloured glass, it will be desirable to state in general terms
the colours or range of colours which can be produced in various kinds
of glass by the introduction of those chemical elements which are
ordinarily used in this way. In general terms it may be said that the
lighter elements do not as a rule tend to the production of coloured
glasses, while the heavier elements, so far as they can be retained in
the glass in either solution or suspension, tend to produce an intense
colouring effect. The element lead appears to form a striking exception
to this rule, but this is due to the fact that while the silicates
of most of the other heavy elements are more or less unstable, the
silicate of lead is very stable, and can only be decomposed by the
action of reducing agents. When lead silicates are decomposed in this
way, however, the resulting glass immediately receives an exceedingly
deep colour, being turned a deep opaque black, although in very thin
layers the colour is decidedly brown. On the other hand, glasses
very rich in lead are always decidedly yellow in colour, and it has
been shown that this coloration is due to the natural colour of lead
silicates and not to the presence of impurities. What has just been
said of lead applies, with only very slight modification, also to the
rare metal thallium and its compounds, which have been introduced into
glass for special purposes. Leaving these two exceptional bodies on
one side, we now pass to a consideration of the elements in the order
of their chemical grouping. The rare elements will not be considered
except in certain cases where their presence in traces is liable to
affect results attained in practice.
The _Alkali Metals_, sodium, potassium, lithium, etc., and their
compounds, have no specific colouring effect, although the presence
of soda or of potash in a glass affects the colours produced by such
substances as manganese, nickel, selenium, etc.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Elsewhere in the archive
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account