The chemical behaviour of glass surfaces, to which we have already
referred, is of the utmost importance to all users of glass. The
relatively neutral chemical behaviour of glass is, in fact, one of its
most useful properties, and, next to its transparency, most frequently
the governing factor in its employment for various purposes. Thus the
entire use of glass for table-ware depends primarily upon the fact
that it does not appreciably affect the composition and flavour of
edible solids or liquids with which it is brought into contact--a
property which is only very partially shared even by the noble metals.
Again, the use of glass windows in places exposed to the weather would
not be feasible if window-glass were appreciably attacked by the
action of water or of the gases of the atmosphere. For these general
purposes, it is true, most ordinary glasses are adequately resistant,
but this degree of perfection in this respect is only the outcome of
the centuries of experience which the practical glass-maker has behind
him in the manufacture and behaviour of such glass. When, however, a
higher degree of chemical resistance is required for special purposes,
as for instance when glass is called upon to resist exposure to hot,
damp climates, or is intended to contain corrosive liquids, the rules
which are an adequate guide to the glass-maker in meeting ordinary
requirements are no longer sufficient, particularly when the glass
is expected to meet other stringent requirements as well. It has, in
fact, frequently happened that a glass-maker, in striving to improve
the colour or quality of his glass, as regards freedom from defects,
brilliancy of surface, etc., has spoilt the chemical durability of his
products. The reason lies in the fact, long known in general terms,
that an increased alkali content reduces the chemical resistance
of glass, while at the same time such an increase of alkali is the
readiest means whereby the glass-maker can improve his glass in other
respects by making it more fusible and easier to work in every way.
This subject of the chemical stability of glass surfaces attracted
much attention during the later part of last century, and careful
investigations on the subject were carried out, particularly at the
German Reichsanstalt (Imperial Physical Laboratory) at Charlottenburg.
Here also the labours of Schott and Abbé proved helpful, until at the
present time such glass as that used by the Jena firm in the production
of laboratory ware, and certain other special glasses of that kind, are
fitted to meet the most stringent requirements.
Public-domain text, read in full here on John Shaqi.
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