Leaving aside the inferior glasses, containing, generally, more than 15
per cent. of alkali, the behaviour of glass surfaces to the principal
chemical agents may be summed up in the following statements. Pure
water attacks all glass to a greater or lesser extent; in the best
glasses the prolonged action of cold water merely extracts a minute
trace of alkalies, but in less perfect kinds the extraction of alkali
is considerable on prolonged exposure even in the cold, and becomes
rapidly more serious if the temperature is raised. Superheated water,
_i.e._, water under steam pressure, becomes an active corroding agent,
and the best glasses can only resist its action for a limited time. For
the gauge-glass tubes of steam boilers working at the high pressures,
which are customary at the present time, specially durable glasses
are required and can be obtained, although many of the gauge-tubes
ordinarily sold are quite unfit for the purpose, both from the present
point of view and from that of strength and “thermal endurance.”
In certain classes of glass, the action of water, especially when hot,
is not entirely confined to the surface, some water penetrating into
the mass of the glass to an appreciable depth. The exact mechanism of
this action is not known, but the writer inclines to the view that it
arises from a partial hydration of some of the silica or silicates
present in the glass. If such glasses be dried in the ordinary way and
subsequently heated, the surface will be riddled with minute cracks,
some glass may even flake off, and the whole surface will be dulled. As
such penetrating action sometimes takes place--in the poorer kinds of
glass--by the action of atmospheric moisture when the glass is merely
stored in a damp place, it is often mistaken for “devitrification.”
This latter action, however, is not known to occur at the ordinary
temperature, although glass when heated in a flame frequently shows
the phenomenon; it is, however, entirely distinct from the surface
“corrosion” just described. Water containing alkaline substances in
solution acts upon all glasses in a relatively rapid manner; it acts
by first abstracting silica from the glass, the alkali and lime being
dissolved or mechanically removed at a later stage. Water containing
acid bodies in solution--_i.e._, dilute acid--on the other hand acts
upon most varieties of glass decidedly less energetically than even
pure water, and much less vigorously than alkaline solutions; this
peculiar behaviour probably depends upon the tendency of acids to
prevent the hydration of silica, this substance being thereby enabled
to act as a barrier to the solvent action of the water upon the
alkaline constituents of the glass. The better varieties of glass are
also practically impervious to the action of strong acids, although
certain of these, such as phosphoric and hydrofluoric, exert a rapid
action on all kinds of glass. Only certain special glasses, containing
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