The dimming process in the case of the less resistant glasses is not
only confined to the formation of alkaline carbonates; the films of
alkaline solution which are formed on the surface of glass form a ready
breeding-ground for certain forms of bacteria and fungi, whose growth
occurs partly at the expense of the glass itself; the precise nature of
these actions has not been fully studied, but there can be little doubt
that silicate minerals--and glass is to be reckoned among these--are
subject to bacterial decomposition, a well-known example in another
direction being the “maturing” of clays by storage in the dark, the
change in the clay being accompanied by an evolution of ammonia gas. In
the case of glass it has been shown that specks of organic dust falling
upon a surface give rise to local decomposition. In this connection it
is interesting to note the effect of the presence of a small proportion
of boric acid in some glasses. The presence of this ingredient in
small proportions is known to render the glass more resistant to
atmospheric agencies, and more especially to render it less sensitive
to the effects of organic dust particles lying upon the surface. It
has been suggested--probably rightly--that the boric acid, entering
into solution in the film of surface moisture, exerts its well-known
antiseptic properties, thus protecting the glass from bacterial and
fungoid activity.
The durability of glass under the action of atmospheric agents is a
matter of such importance that numerous efforts have been made to
establish a satisfactory test whereby this property of a given glass
may be ascertained without actually awaiting the results of experience
obtained by actual use under unfavourable conditions. One of the
earliest of the tests proposed consisted in exposing surfaces of the
glass to the vapour of hydrochloric acid. For this purpose some strong
hydrochloric acid is placed in a glass or porcelain basin, and strips
of the glass to be tested are placed across the top of the basin, the
whole being covered with a bell-jar. After several days the glass is
examined, and as a rule the less stable glasses show a dull, dimmed
surface as compared with the more stable ones. A more satisfactory
form of test depends upon the fact that aqueous ether solutions react
readily with the less stable kinds of glass; if a suitable dye, such as
iod-eosin, be dissolved in the water-ether solution, then the effect
upon the less stable glasses when immersed in the solution is the
formation of a strongly adherent pink film. The density or depth of
colour of this film may be regarded as measuring the stability of the
glass; the best kinds of glass remain practically free from coloured
film even on prolonged exposure. A test of a somewhat different kind
is one devised in its original form by Dr. Zschimmer, of the Jena
glass works; this depends upon the fact that the disintegrating action
of moist air can be very much accelerated if both the moisture and
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