an excessive proportion of basic constituents and of such substances as
boric or phosphoric acid, are capable of being completely decomposed by
the action of strong acids, such as hydrochloric or nitric, the bases
entering into combination with the acids, while the silicic and other
acids are liberated.
In connection with the action of acids upon glass, mention should be
made of certain special actions that are of practical importance. The
dissolving action of hydrofluoric acid upon glass is, of course, well
known. It is used in practice both in the liquid and gaseous form, and
also in that of compounds from which it is readily liberated (such
as ammonium or sodium fluoride), for the purpose of “etching” glass,
and also in decomposing glass for purposes of chemical analysis.
Next in importance ranks the action of carbonic acid gas upon glass,
especially in the presence of moisture. The action in question is
probably indirect in character; the moisture of the air, condensing
upon the surface of the glass, first exerts its dissolving action, and
thus draws from the glass a certain quantity of alkali, which almost
certainly at first goes into solution as alkali hydrate (potassium or
sodium hydroxide); this alkaline solution, however, rapidly absorbs
carbonic acid from the air, and the carbonate of the alkali is formed.
If the glass dries, this carbonate forms a coating of minute crystals
on the surface of the glass, giving it a dull, dimmed appearance;
this, however, only occurs ordinarily with soda glasses, since the
carbonate of potassium is too hygroscopic to remain in the dry solid
state in any ordinary atmosphere. Potash glasses are, as such, no more
stable chemically than soda glasses, but they are for the reason just
given less liable to exhibit a dim surface. If the dimming process,
in the case of a soda glass, has not gone too far, the brightness of
the surface of the glass may be practically restored by washing it
with water, in which the minute crystals of carbonate of soda readily
dissolve, while separated silica is removed mechanically. An attempt
made to clean the same dimmed surface by dry wiping would only result
in finally ruining the surface, since the small sharp crystals of
carbonate of soda would be rubbed about over the surface, scratching it
in all directions.
Public-domain text, read in full here on John Shaqi.
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